Orientation-dependent kinetics of heterogeneous electron transfer for cytochrome c immobilized on gold: Electrochemical determination and theoretical prediction (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Orientation-dependent kinetics of heterogeneous electron transfer for cytochrome c immobilized on gold: Electrochemical determination and theoretical prediction (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Alternative label

• Bortolotti, C; Borsari, M; Sola, M; Chertkova, R; Dolgikh, D; Kotlyar, A; Facci, P (2007)
  Orientation-dependent kinetics of heterogeneous electron transfer for cytochrome c immobilized on gold: Electrochemical determination and theoretical prediction
  in Journal of physical chemistry. C
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bortolotti, C; Borsari, M; Sola, M; Chertkova, R; Dolgikh, D; Kotlyar, A; Facci, P (literal)

Pagina inizio

• 12100 (literal)

Pagina fine

• 12105 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 111 (literal)

Rivista

• Journal of physical chemistry. C (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• INFM, CNR, Natl Ctr Nanostruct & Biosyst Surfaces S3, I-41100 Modena, Italy; Tel Aviv Univ, George S Wise Fac Life Sci, Dept Biochem, Ramat Aviv, Israel; Univ Modena & Reggio Emilia, Dept Chem, Modena, Italy; Russian Acad Sci, Shemyakin Ovchinnikov Inst Bioorgan Chem, Moscow, Russia (literal)

Titolo

• Orientation-dependent kinetics of heterogeneous electron transfer for cytochrome c immobilized on gold: Electrochemical determination and theoretical prediction (literal)

Abstract

• A systematic comparison between electron-transfer rate constants measured electrochemically for different cysteine-bearing mutants of cytochrome c chemisorbed on gold surfaces in different orientations has been performed. Experimental data have been correlated with electronic coupling theoretical estimates obtained from two different empirical models for the kinetics of protein electron transfer, the tunneling pathway model and the average packing density model. The results indicate that both models also hold in the case of immobilized redox proteins, outlining their role in the rational design of optimized electron-transfer-based bioinorganic interfaces. (literal)

Prodotto di

• Nanobiosistemi (MD.P06.010.001) (Modulo)

Autore CNR

• Marco Sola (Unità di personale esterno)
• PAOLO FACCI (Persona)

Insieme di parole chiave

• Parole chiave di "Orientation-dependent kinetics of heterogeneous electron transfer for cytochrome c immobilized on gold: Electrochemical determination and theoretical prediction" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• PAOLO FACCI (Persona)
• Marco Sola (Unità di personale esterno)

Prodotto

• Nanobiosistemi (MD.P06.010.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of physical chemistry. C (Rivista)

Insieme di parole chiave di

• Parole chiave di "Orientation-dependent kinetics of heterogeneous electron transfer for cytochrome c immobilized on gold: Electrochemical determination and theoretical prediction" (Insieme di parole chiave)