http://www.cnr.it/ontology/cnr/individuo/prodotto/ID182854
Wetting properties of flat and porous silicon surfaces coated with a spiropyran (Articolo in rivista)
- Type
- Label
- Wetting properties of flat and porous silicon surfaces coated with a spiropyran (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/la7024878 (literal)
- Alternative label
Davide Dattilo; Lidia Armelao; Giovanni Fois; Giampaolo Mistura; Michele Maggini (2007)
Wetting properties of flat and porous silicon surfaces coated with a spiropyran
in Langmuir; ACS, American chemical society, Washington, DC (Stati Uniti d'America)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Davide Dattilo; Lidia Armelao; Giovanni Fois; Giampaolo Mistura; Michele Maggini (literal)
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- http://pubs.acs.org/doi/full/10.1021/la7024878 (literal)
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- Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy
Univ Padua, ISTM CNR, Dipartimento Sci Chim, I-35131 Padua, Italy
Univ Padua, Dipartimento Fis, I-35131 Padua, Italy (literal)
- Titolo
- Wetting properties of flat and porous silicon surfaces coated with a spiropyran (literal)
- Abstract
- We report the immobilization and characterization of a spiropyran (SP) derivative (1) on smooth Si(I 00) and porous H-terminated silicon surfaces through a thermal hydrosilylation protocol. Under visible light exposure the SP is in a closed, hydrophobic form, whereas under UV irradiation it converts to a polar, hydrophilic open form named merocyanine (MC). The SP-MC photoinduced isomerization gives a small contact angle (CA) change of 9 degrees for smooth Si(100) samples under sequential irradiation cycles with white and UV light. Irradiation of porous silicon (PS) surfaces, under the same conditions, gave a CA change of 11 degrees. Treatment of PS surfaces, bearing the MC form of chromophore 1, with cobalt(11) ions enhances the wettability switching of the PS surface to a much larger extent, giving rise to a CA variation as high as 32 degrees. (literal)
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