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Adsorption and photo-oxidation of 3,4-dihydroxy-cinnamic acid on TiO(2) films (Articolo in rivista)
- Type
- Label
- Adsorption and photo-oxidation of 3,4-dihydroxy-cinnamic acid on TiO(2) films (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.cattod.2008.12.020 (literal)
- Alternative label
Amadelli, R ; Maldotti, A ; Samiolo, L (2009)
Adsorption and photo-oxidation of 3,4-dihydroxy-cinnamic acid on TiO(2) films
in Catalysis Today
(literal)
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- Amadelli, R ; Maldotti, A ; Samiolo, L (literal)
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- ISI Web of Science (WOS) (literal)
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- CNR, ISOF c/o Univ Ferrara, I-44100 Ferrara, Italy
Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy (literal)
- Titolo
- Adsorption and photo-oxidation of 3,4-dihydroxy-cinnamic acid on TiO(2) films (literal)
- Abstract
- The photo-oxidation of 3,4-dihydroxy-cinnamic acid (DHCA) is investigated on TiO(2) films prepared from commercial Degussa P-25 (FP25 films) and from colloidal TiO(2) prepared by the sol-gel method (FSG films). Photo-oxidation rates have been found to be inversely correlated to the amount of adsorbed species. The extent of adsorption increases as the solution pH increases from 1 to 4 and is more pronounced in the case of FP25 samples for which the amount of adsorbed species is 2.7 x 10(-10) Mol cm(-2), i.e. about threefold higher than for the FSG case. Analysis of DHCA adsorption on TiO(2) suspensions provided information complementary to that collected on films. Diffuse reflectance UV-visible and FTIR spectra of adsorbed DHCA are conspicuously different for the two types of films. (literal)
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