Structural and collisional relaxations in liquids and supercritical fluids (Articolo in rivista)

Type
Label
  • Structural and collisional relaxations in liquids and supercritical fluids (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Alternative label
  • Bencivenga, F; Cunsolo, A; Krisch, M; Monaco, G; Orsingher, L; Ruocco, G; Sette, F; Vispa, A (2007)
    Structural and collisional relaxations in liquids and supercritical fluids
    in Physical review letters (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bencivenga, F; Cunsolo, A; Krisch, M; Monaco, G; Orsingher, L; Ruocco, G; Sette, F; Vispa, A (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 98 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • European Synchrotron Radiat Facil, F-38043 Grenoble, France; CNR, INFM, SOFT, CRS,ILL,Operat Grp Grenoble, F-38043 Grenoble, France; Univ Trent, Dipartimento Fis, I-38050 Trento, Italy; Univ Roma La Sapienza, Dipartimento Fis, CRS, SOFT,INFM,CNR, I-00185 Rome, Italy; Univ Perugia, Dipartimento Fis, I-06123 Perugia, Italy (literal)
Titolo
  • Structural and collisional relaxations in liquids and supercritical fluids (literal)
Abstract
  • The dynamic structure factor S(Q,omega) of both associated (water and ammonia) and simple fluids (nitrogen and neon) has been determined by high-resolution inelastic x-ray scattering in the 2-14 nm(-1) momentum transfer range. A line-shape analysis with a generalized hydrodynamic model was used to study the involved relaxation process and to characterize its strength and time scale. We observe that in the liquid phase such a process is governed by rearrangements of intermolecular bonds, whereas in the supercritical region it assumes a collisional nature. (literal)
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