http://www.cnr.it/ontology/cnr/individuo/prodotto/ID182130
Electrodeposition of lead dioxide from methanesulfonate solutions (Articolo in rivista)
- Type
- Label
- Electrodeposition of lead dioxide from methanesulfonate solutions (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.jpowsour.2008.10.054 (literal)
- Alternative label
Velichenko, A.B.; Amadelli, R.; Gruzdeva, E.V. ; Luk'yanenko, T. V.; Danilov, F. I. (2009)
Electrodeposition of lead dioxide from methanesulfonate solutions
in Journal of power sources (Print); ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Velichenko, A.B.; Amadelli, R.; Gruzdeva, E.V. ; Luk'yanenko, T. V.; Danilov, F. I. (literal)
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- ISI Web of Science (WOS) (literal)
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- Ukrainian State Univ Chem Technol, Dept Phys Chem, UA-49005 Dnepropetrovsk, Ukraine
ISOF CNR c/o Univ Ferrara, Dept Chem, I-44100 Ferrara, Italy (literal)
- Titolo
- Electrodeposition of lead dioxide from methanesulfonate solutions (literal)
- Abstract
- Lead dioxide electrodeposition from methanesulfonic media and physicochemical properties of the resulting oxide were studied in this work to improve anodic process at PbO(2)/Pb(2+) electrode of How battery. The presence of methanesulfonate ions in the electrodeposition solution causes only a quantitative difference in the PbO(2) electrodeposition process without apparently changing the reaction mechanism. In methanesulfonic media PbO(2) electrodeposition rate is higher than in nitrate solutions. Current efficiency of PbO(2) formation depends on electrode potential (or deposition current density), electrolyte composition (concentration of Pb(2+) and methanesulfonate ions), hydrodynamic conditions, pH and temperature of the solution. It is important to note that thick PbO(2) coatings (up to 2 mm) with good mechanical properties and adhesion to the substrate can be deposited in a wide range of current density (2-100 mA cm(-2)). (literal)
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