Adsorption of 3,4-ethylenedioxytiophene (EDOT) on noble metal surfaces: a photoemission and x-ray absorption study (Articolo in rivista)

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Label
  • Adsorption of 3,4-ethylenedioxytiophene (EDOT) on noble metal surfaces: a photoemission and x-ray absorption study (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.elspec.2009.03.014 (literal)
Alternative label
  • L. Pasquali; F. Terzi; M. Montecchi; B.P. Doyle; J. Lukkari; B. Zanfrognini; R. Seeber; S. Nannarone; (2009)
    Adsorption of 3,4-ethylenedioxytiophene (EDOT) on noble metal surfaces: a photoemission and x-ray absorption study
    in Journal of electron spectroscopy and related phenomena (Print); ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • L. Pasquali; F. Terzi; M. Montecchi; B.P. Doyle; J. Lukkari; B. Zanfrognini; R. Seeber; S. Nannarone; (literal)
Pagina inizio
  • 114 (literal)
Pagina fine
  • 119 (literal)
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  • 172 (literal)
Rivista
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  • 5 (literal)
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  • 1-3 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento di Ingegneria dei Materiali e dell'Ambiente, Universita? di Modena e Reggio Emilia, Via Vignolese 905, 41100 Modena, Italy; Dipartimento di Chimica, Universita? di Modena e Reggio Emilia, Via Campi 183, 41100 Modena, Italy; Laboratorio Nazionale TASC, INFM-CNR, s.s.14, km 163.5 in Area Science Park, 34012 Trieste, Italy; Department of Chemistry, University of Turku, FIN-20014 Turku, Finland; Turku University Centre for Materials and Surfaces (MATSURF), University of Turku, Turku, Finland; (literal)
Titolo
  • Adsorption of 3,4-ethylenedioxytiophene (EDOT) on noble metal surfaces: a photoemission and x-ray absorption study (literal)
Abstract
  • The adsorption of 3,4-ethylenedioxythiophene (EDOT) on Au and Pt surfaces is studied by core level and valence band photoemission using synchrotron radiation and by near edge X-ray absorption spectroscopy. To closer simulate real applications, the films are grown from aqueous solution at room temperature and are compared to an 'ideal' film prepared by dosing the molecules from the vapour phase on a clean Au(1 1 1) single crystal. The S 2p. C 1s and O 1s levels show multiple components which are associated to molecular fragmentation. NEXAFS confirms that fragmentation takes place at the surface. Thiophene species as well as alkyl chains and S(n) species are identified as the most probable fragmentation products. (literal)
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