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Site of Mn in Mn delta-doped GaAs: X-ray absorption spectroscopy (Articolo in rivista)
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- Site of Mn in Mn delta-doped GaAs: X-ray absorption spectroscopy (Articolo in rivista) (literal)
- Anno
- 2006-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevB.73.035314 (literal)
- Alternative label
d'Acapito, F (d'Acapito, F); Smolentsev, G (Smolentsev, G); Boscherini, F (Boscherini, F); Piccin, M (Piccin, M); Bais, G (Bais, G); Rubini, S (Rubini, S); Martelli, F (Martelli, F); Franciosi, A (Franciosi, A) (2006)
Site of Mn in Mn delta-doped GaAs: X-ray absorption spectroscopy
in Physical review. B, Condensed matter and materials physics
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- d'Acapito, F (d'Acapito, F); Smolentsev, G (Smolentsev, G); Boscherini, F (Boscherini, F); Piccin, M (Piccin, M); Bais, G (Bais, G); Rubini, S (Rubini, S); Martelli, F (Martelli, F); Franciosi, A (Franciosi, A) (literal)
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- ISI Web of Science (WOS) (literal)
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- 1. CRG, GILDA, ESRF, CNR,INFM,OGG, F-38043 Grenoble, France
2. Rostov State Univ, Dept Phys, Rostov Na Donu 344006, Russia
3. Univ Bologna, Dept Phys, I-40127 Bologna, Italy
4. Univ Bologna, CNISM, I-40127 Bologna, Italy
5. CNR, INFM, Lab Nazl TASC, I-34012 Trieste, Italy (literal)
- Titolo
- Site of Mn in Mn delta-doped GaAs: X-ray absorption spectroscopy (literal)
- Abstract
- In order to determine the local structure of Mn in delta-doped GaAs layers we have carried out an x-ray absorption spectroscopy experiment at the Mn-K edge in samples grown by molecular beam epitaxy with and without Be co-doping. Mn-Mn atomic correlations have not been found within similar to 5 A radius, ruling out the presence of metallic clusters or local Mn enrichment. In samples deposited at 300 degrees C, Mn substitutionally occupies the Ga site with a local expansion (approximate to 2%) of the first-neighbor distance with respect to GaAs; the second neighbors remain at a distance very close to that of the host lattice, indicating that the structural perturbation induced by Mn is very localized. Ab initio simulation of the x-ray absorption near edge structure spectra confirmed that Mn enters the Ga, rather than the As, site. Samples grown at 450 degrees C exhibit a reduction of the first shell coordination number, suggesting the initial phases of MnAs precipitation. In the case of Be co-doping the downward shift of the Fermi energy leads to the appearance of Mn in tetrahedral interstitial sites, of which we provide a previously unavailable local structural description. (literal)
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