Isothermal vapour + liquid equilibrium measurements and correlation for the dimethyl ether + 1,1,1,2,3,3,3-heptafluoropropane and the propane + 1,1,1,2,3,3,3-heptafluoropropane systems (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Isothermal vapour + liquid equilibrium measurements and correlation for the dimethyl ether + 1,1,1,2,3,3,3-heptafluoropropane and the propane + 1,1,1,2,3,3,3-heptafluoropropane systems (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.fluid.2004.07.001 (literal)

Alternative label

• Bobbo S.; Fedele L.; Scattolini M.; Camporese R.; Stryjek R. (2004)
  Isothermal vapour + liquid equilibrium measurements and correlation for the dimethyl ether + 1,1,1,2,3,3,3-heptafluoropropane and the propane + 1,1,1,2,3,3,3-heptafluoropropane systems
  in Fluid phase equilibria; ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bobbo S.; Fedele L.; Scattolini M.; Camporese R.; Stryjek R. (literal)

Pagina inizio

• 119 (literal)

Pagina fine

• 123 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0378381204003176 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 224 (literal)

Rivista

• Fluid phase equilibria (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 5 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)
• Google Scholar (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1-4 : Consiglio Nazionale delle Ricerche, Istituto per le Tecnologie della Costruzione, Sede di Padova, Corso Stati Uniti 4, 35127 Padova, Italy; 5 : Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland (literal)

Titolo

• Isothermal vapour + liquid equilibrium measurements and correlation for the dimethyl ether + 1,1,1,2,3,3,3-heptafluoropropane and the propane + 1,1,1,2,3,3,3-heptafluoropropane systems (literal)

Abstract

• Isothermal vapour + liquid equilibria (VLE) data were measured for the dimethylether (RE170) + 1,1,1,2,3,3,3-heptafluoropropane (R227ea) and propane (R290) + R227ea systems at 278.15, 293.15 and 308.15 K, using a static analytical method. The phase compositions at equilibrium were measured by gas chromatography. The experimental estimated accuracies are ±0.02K for temperature, ±1 kPa for pressure, and ±0.003 in mole fraction for both liquid and vapour phase composition. The R290 + R227ea system shows strong positive deviations from Raoult's law, while the RE170 + R227ea system shows strong negative deviations. The deviations from Raoult's law observed for the RE170 + R227ea system are attributed to hydrogen bonding. On the basis of the homomorphic concept, the excess Gibbs free energy (gE) of the H-bonding is estimated as the difference between the gE of corresponding homomorphic pairs of systems. The experimental data are firstly regressed with the Carnahan-Starling-De Santis (CSD) equation of state (EoS) together with the classical mixing rule, and then by means of the Redlich- Kwong-Soave (RKS) EoS, with the Huron-Vidal mixing rule (HV), using the NRTL equation for the gE at infinite pressure. Better results are achieved with the latter, and the gE of these two systems is calculated using the resulting coefficients. On the basis of the RKS-HV-NRTL model, a comparison with the available literature data is performed. (literal)

Editore

• ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS (Editore)

Prodotto di

• Risparmio energetico e sostenibilità ambientale di sistemi di condizionamento dell'aria e refrigerazione (SP.P04.004.001) (Modulo)

Autore CNR

• ROMAN STRYJEK (Unità di personale esterno)
• SERGIO BOBBO (Unità di personale interno)
• LAURA FEDELE (Persona)
• MAURO SCATTOLINI (Unità di personale interno)
• ROBERTO CAMPORESE (Persona)

Insieme di parole chiave

• Parole chiave di "Isothermal vapour + liquid equilibrium measurements and correlation for the dimethyl ether + 1,1,1,2,3,3,3-heptafluoropropane and the propane + 1,1,1,2,3,3,3-heptafluoropropane systems" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• MAURO SCATTOLINI (Unità di personale interno)
• SERGIO BOBBO (Unità di personale interno)
• ROBERTO CAMPORESE (Persona)
• LAURA FEDELE (Persona)
• ROMAN STRYJEK (Unità di personale esterno)

Prodotto

• Risparmio energetico e sostenibilità ambientale di sistemi di condizionamento dell'aria e refrigerazione (SP.P04.004.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Fluid phase equilibria (Rivista)

Editore di

• ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS (Editore)

Insieme di parole chiave di

• Parole chiave di "Isothermal vapour + liquid equilibrium measurements and correlation for the dimethyl ether + 1,1,1,2,3,3,3-heptafluoropropane and the propane + 1,1,1,2,3,3,3-heptafluoropropane systems" (Insieme di parole chiave)