Sequence determination in aliphatic poly(ester amide)s by matrix-assisted laser desorption/ionization time-of-flight and time-of-flight/time-of-flight tandem mass spectrometry (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Sequence determination in aliphatic poly(ester amide)s by matrix-assisted laser desorption/ionization time-of-flight and time-of-flight/time-of-flight tandem mass spectrometry (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/rcm.2075 (literal)

Alternative label

• P. Rizzarelli; C. Puglisi; G. Montaudo (2005)
  Sequence determination in aliphatic poly(ester amide)s by matrix-assisted laser desorption/ionization time-of-flight and time-of-flight/time-of-flight tandem mass spectrometry
  in RCM. Rapid communications in mass spectrometry
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• P. Rizzarelli; C. Puglisi; G. Montaudo (literal)

Pagina inizio

• 2407 (literal)

Pagina fine

• 2418 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Times Cited: 10 (from Web of Science) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 19 (literal)

Rivista

• RCM. Rapid communications in mass spectrometry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• No. Citazione=7; Autocitazione=3; Motore utilizzato per le citazioni=Isiwebofknowledge.com (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 12 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 17 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR ICTP Catania Università di Catania (literal)

Titolo

• Sequence determination in aliphatic poly(ester amide)s by matrix-assisted laser desorption/ionization time-of-flight and time-of-flight/time-of-flight tandem mass spectrometry (literal)

Abstract

• Poly(ester amide)s from dimethyl sebacate or sebacic acid and 2-aminoethanol or 4-amino-1-butanol were characterized by post-source decay matrix-assisted laser desorption/ionization time-of-flight (PSD-MALDI-TOF) and time-of-flight/time-of-flight tandem mass spectrometry (MALDI-TOF/TOF-MS/MS). Sodiated oligomers were selected as precursor ions for dissociation studies. PSD analysis was performed on dimethyl sebacate, dicarboxylic, carboxylic and amino alcohol, and diamino alcohol terminated oligomers. PSD-MALDI-TOF mass spectra yielded information on the fragmentation mechanisms of the poly(ester amide) chains, showing that the main cleavages proceed through a beta-hydrogen transfer rearrangement. MALDI-TOF/TOF-MS/MS provided structural information concerning ester/amide sequences in the polymer chains. As expected, together with the ions appearing in the PSD-MALDI mass spectrum, several new abundant fragment ions in the low-mass range are present in MALDI-TOF/TOF-MS/MS spectra. These new product ions proved to be diagnostic and made it possible to establish the presence of random sequences of ester and amide bonds in the poly(ester amide)s samples. (literal)

Prodotto di

• 4. Sistemi polimerici innovativi ad elevate prestazioni per applicazioni biomediche ed ambientali (PM.P02.009.001) (Modulo)
• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)

Autore CNR

• CONCETTO PUGLISI (Unità di personale interno)
• PAOLA RIZZARELLI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Sequence determination in aliphatic poly(ester amide)s by matrix-assisted laser desorption/ionization time-of-flight and time-of-flight/time-of-flight tandem mass spectrometry" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• CONCETTO PUGLISI (Unità di personale interno)
• PAOLA RIZZARELLI (Unità di personale interno)

Prodotto

• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)
• 4. Sistemi polimerici innovativi ad elevate prestazioni per applicazioni biomediche ed ambientali (PM.P02.009.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• RCM. Rapid communications in mass spectrometry (Rivista)

Insieme di parole chiave di

• Parole chiave di "Sequence determination in aliphatic poly(ester amide)s by matrix-assisted laser desorption/ionization time-of-flight and time-of-flight/time-of-flight tandem mass spectrometry" (Insieme di parole chiave)