Structure, morphology and crystallization process of isotactic polypropylene/hydrogenated hydrocarbon resin blends (Articolo in rivista)

Type
Label
  • Structure, morphology and crystallization process of isotactic polypropylene/hydrogenated hydrocarbon resin blends (Articolo in rivista) (literal)
Anno
  • 2004-01-01T00:00:00+01:00 (literal)
Alternative label
  • C. Silvestre, S. Cimmino , J. S. Lin (2004)
    Structure, morphology and crystallization process of isotactic polypropylene/hydrogenated hydrocarbon resin blends
    in Journal of polymer science. Part B, Polymer physics
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • C. Silvestre, S. Cimmino , J. S. Lin (literal)
Pagina inizio
  • 3368 (literal)
Pagina fine
  • 3379 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 42 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • No. Citazione=1; Autocitazione=0; Motore utilizzato per le citazioni=Google Scholar. (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, Oak Ridge National Laboratory, University of Tennessee. (literal)
Titolo
  • Structure, morphology and crystallization process of isotactic polypropylene/hydrogenated hydrocarbon resin blends (literal)
Abstract
  • The structure, morphology, and isothermal and nonisothermal crystallization of isotactic polypropylene/low-molecular-mass hydrocarbon resin blends (iPP/HR) (up to 20% in weight of HR) have been studied, using optical and electron microscopy, wide- and small-angle X-ray and differential scanning calorimetry. New structures and morphologies can be activated, using appropriate preparation and crystallization conditions and blend composition. For every composition and crystallization condition, iPP crystallizes in -form, with a spherulitic morphology. The size of iPP spherulites increases with resin content, whereas the long period decreases. In the range of crystallization temperatures investigated, HR modifies the birefringence of iPP spherulites, favoring the formation of radial lamellae and changing the ratio between tangential and radial lamellae. Spherulitic radial growth rates, overall crystallization rates, and melting temperatures are strongly affected by resin, monotonically decreasing with resin content. This confirms miscibility in the melt between the two components of the blends. (literal)
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