Influence of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) on miscibility and properties of atactic poly(methyl methacrylate) (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Influence of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) on miscibility and properties of atactic poly(methyl methacrylate) (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/pi.1464 (literal)

Alternative label

• S. Cimmino; E. D’Alma; M. L. Di Lorenzo; C. Silvestre (2004)
  Influence of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) on miscibility and properties of atactic poly(methyl methacrylate)
  in Polymer international
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• S. Cimmino; E. D’Alma; M. L. Di Lorenzo; C. Silvestre (literal)

Pagina inizio

• 809 (literal)

Pagina fine

• 814 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 53 (literal)

Rivista

• Polymer international (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• No. Citazione=0; Autocitazione=0; Motore utilizzato per le citazioni=Google Scholar. (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 6 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR (literal)

Titolo

• Influence of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) on miscibility and properties of atactic poly(methyl methacrylate) (literal)

Abstract

• Miscibility and properties of two atactic poly(methyl methacrylate)-based blends [containing 10 and 20% of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)] have been investigated as a function of thermal treatments. Differential scanning calorimetry and dynamic mechanical thermal analysis of blends quenched in liquid nitrogen or ice/water, after annealing at T > 190 °C, showed a single glass transition temperature, indicating miscibility of the components for the time-temperature history. Two glass transition temperatures, equal to those of the pure components, are instead found for blends after annealing at T < 190 °C. Scanning electron microscopy confirmed the homogeneity for the former quenched blends and phase separation for the latter. These results indicate the presence of an upper critical solution temperature (UCST). Tensile experiments, performed on two series of samples annealed at temperatures above and below the UCST, showed that the copolyester induces a decrease of Young's modulus and stresses at yielding and break points, and a marked increase of elongation at break. Differences in tensile properties between the two series of annealed blends are accounted for by the physical state of the components at room temperature after annealing above or below the UCST. (literal)

Prodotto di

• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)

Autore CNR

• CLARA MARIA IMMACOLATA SILVESTRE (Persona)
• SOSSIO CIMMINO (Unità di personale interno)
• MARIA LAURA DI LORENZO (Unità di personale interno)

Incoming links:

Autore CNR di

• SOSSIO CIMMINO (Unità di personale interno)
• MARIA LAURA DI LORENZO (Unità di personale interno)
• CLARA MARIA IMMACOLATA SILVESTRE (Persona)

Prodotto

• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Polymer international (Rivista)