The free jet microwave spectrum of 2-phenylethylamine-water (Articolo in rivista)

Type
Label
  • The free jet microwave spectrum of 2-phenylethylamine-water (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/c003513k (literal)
Alternative label
  • Sonia Melandri; Assimo Maris; Barbara M. Giuliano; Laura B. Favero; Walther Caminati (2010)
    The free jet microwave spectrum of 2-phenylethylamine-water
    in PCCP. Physical chemistry chemical physics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Sonia Melandri; Assimo Maris; Barbara M. Giuliano; Laura B. Favero; Walther Caminati (literal)
Pagina inizio
  • 10210 (literal)
Pagina fine
  • 10214 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 12 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 35 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento Chim G Ciamician, Bologna, Italy; Dipartimento Chim G Ciamician, Bologna, Italy; Dipartimento Chim G Ciamician, Bologna, Italy; ISMN CNR Sede Bologna, I-40129 Bologna, Italy; Dipartimento Chim G Ciamician, Bologna, Italy; (literal)
Titolo
  • The free jet microwave spectrum of 2-phenylethylamine-water (literal)
Abstract
  • We observed the rotational spectrum of the 1:1 molecular adduct between 2-phenylethylamine and water (normal and H(2)(18)O species) by free jet absorption microwave spectroscopy in the frequency region 60-78 GHz. The dominant spectrum belongs to the structure where the PEA moiety is in the most stable gauche conformation and the water molecule is hydrogen bound to the nitrogen lone pair. The orientation of the water molecule is such that the oxygen atom is almost equidistant (ca. 2.5 angstrom) from the closest methylenic and aromatic hydrogen atoms. (literal)
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