On the Preparation and Characterization of Polyethylene/Polyamide Blends by Melt Processing in the Presence of an Ethylene/Acrylic Acid Copolymer and of New Phosphazene Compounds (Articolo in rivista)

Type
Label
  • On the Preparation and Characterization of Polyethylene/Polyamide Blends by Melt Processing in the Presence of an Ethylene/Acrylic Acid Copolymer and of New Phosphazene Compounds (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/macp.200600332 (literal)
Alternative label
  • R. Scaffaro, M. C. Mistretta, F. P. La Mantia, M. Gleria, R. Bertani, F. Samperi, C. Puglisi (2006)
    On the Preparation and Characterization of Polyethylene/Polyamide Blends by Melt Processing in the Presence of an Ethylene/Acrylic Acid Copolymer and of New Phosphazene Compounds
    in Macromolecular chemistry and physics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • R. Scaffaro, M. C. Mistretta, F. P. La Mantia, M. Gleria, R. Bertani, F. Samperi, C. Puglisi (literal)
Pagina inizio
  • 1986 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 207 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • No. Citazione=1; Autocitazione=1; Motore utilizzato per le citazioni=Isiwebofknowledge.com (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, Università di Palermo, Università di PADOVA. (literal)
Titolo
  • On the Preparation and Characterization of Polyethylene/Polyamide Blends by Melt Processing in the Presence of an Ethylene/Acrylic Acid Copolymer and of New Phosphazene Compounds (literal)
Abstract
  • Samples of HDPE and PA6 have been meltprocessed in the presence of two new phosphazene compounds, CP-2EPOX and CP-2OXA together with an ethylene/acrylic acid copolymer. The blends have been prepared in an industrial twin-screw extruder by using PA6 and PE in weight ratios of 25/75 and 75/25. When used, 5 phr of EAA and 0.2 phr of CP have been added. The materials have been completely characterized from a rheological, morphological, and mechanical point of view. The results indicate that the additives used caused an increase in the rupture tensile properties, of the impact strength and viscosity especially in the PE-rich blend in the presence of CP-2EPOX. This result can be attributed both to a chain extension reaction on EAA and PA6 phases and on compatibilization effect due to the possible formation of EAA-g-PA6 copolymers. This latter occurrence is suggested by an improved adhesion between the phases and by an increased turbidity observed in the Molau tests. Between the two compatibilizers, the CP-2EPOX displays the overall best results, especially for the PE-based blends. (literal)
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