The crystallization and melting processes of poly(L-lactic acid) (Articolo in rivista)

Type
Label
  • The crystallization and melting processes of poly(L-lactic acid) (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Alternative label
  • M. L. Di Lorenzo (2006)
    The crystallization and melting processes of poly(L-lactic acid)
    in Macromolecular symposia
    (literal)
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  • M. L. Di Lorenzo (literal)
Pagina inizio
  • 176 (literal)
Pagina fine
  • 183 (literal)
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  • 234 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • No. Citazione=3; Autocitazione=0; Motore utilizzato per le citazioni=Google Scholar (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR (literal)
Titolo
  • The crystallization and melting processes of poly(L-lactic acid) (literal)
Abstract
  • A throughout investigation of crystallization and melting behavior of poly(L-lactic acid) is detailed in this contribution. Crystallization analyses, conducted in both isothermal and non-isothermal conditions, revealed the occurrence of a sudden acceleration in phase transition rate in the temperature range between 100 and 118 °C. This unusual increase, due to very high rates of spherulite growth, seems not related to morphological changes of PLLA spherulites, nor to unexpected variations in nucleation rate. DSC analyses disclosed multiple melting behavior of PLLA, depending on crystallization temperature. At low temperatures the very high crystallization rates lead to the achievement of low values of crystalline degree, with formation of small and/or defective crystals, which have a large tendency to reorganize into more stable structures during the heating scan that leads to complete fusion. The multiple melting process of PLLA was also analyzed at different heating rates. (literal)
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