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Impact of the starting powder composition on GdSr2RuCu2O8 Melt-Textured Processes (Articolo in rivista)
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- Label
- Impact of the starting powder composition on GdSr2RuCu2O8 Melt-Textured Processes (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1109/TASC.2009.2018551 (literal)
- Alternative label
R. Ciancio; M. Gombos; G. Grimaldi; A. Nigro; A. Vecchione; S. Pace (2009)
Impact of the starting powder composition on GdSr2RuCu2O8 Melt-Textured Processes
in IEEE transactions on applied superconductivity (Print); IEEE-Institute Of Electrical And Electronics Engineers Inc., Piscataway (Stati Uniti d'America)
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- R. Ciancio; M. Gombos; G. Grimaldi; A. Nigro; A. Vecchione; S. Pace (literal)
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- Univ Salerno, Dept Phys ER Caianiello, I-84081 Baronissi, SA, Italy
Univ Salerno, Reg Lab SuperMat, INFM, CNR, I-84081 Baronissi, SA, Italy (literal)
- Titolo
- Impact of the starting powder composition on GdSr2RuCu2O8 Melt-Textured Processes (literal)
- Abstract
- In order to achieve MTG samples with higher oriented volume fractions, we prepared pellets adding either GdSr(2)RuO(6) (Gd1210) or CuO to highly pure Gd1212 powders. X-ray Diffraction (XRD) analysis revealed a substantial difference between the two systems showing that only in Gd1212-Gd1210 samples it is possible to achieve a superconducting phase. The analysis of the two samples microstructures carried out by Scanning Electron Microscopy with implemented Energy Dispersive Spectroscopy (EDS) revealed that in the case of the Gd1212-Gd1210 samples a low concentration of Gd1210 and SrRuO(3) inclusions is observed in a Gd1212 predominant matrix. However, in the Gd1212-CuO samples, micro-sized precipitates of SrRuO(3), islands of Gd(2)CuO(4) are homogeneously distributed throughout a CuO matrix. DTA measurements performed on all the samples confirm the presence of additional solidification reactions in the Gd1212-CuO samples. These features have a profound impact on the transport properties of the two samples. The addition of Gd1210 in highly pure Gd1212 powders has been proved to be a favorable condition to obtain superconducting Gd1212 MTG samples. (literal)
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