http://www.cnr.it/ontology/cnr/individuo/prodotto/ID178122
About oligothiophene self-assembly: From aggregation in solution to solid-state nanostructures (Articolo in rivista)
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- About oligothiophene self-assembly: From aggregation in solution to solid-state nanostructures (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/cm049673x (literal)
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Ph. Lecle`re,*,+,? M. Surin,+ P. Viville,+ R. Lazzaroni,+ A. F. M. Kilbinger,§
O. Henze,§ W. J. Feast,§ M. Cavallini,| F. Biscarini,| A. P. H. J. Schenning,? and
E. W. Meijer? (2004)
About oligothiophene self-assembly: From aggregation in solution to solid-state nanostructures
in Chemistry of materials; American Chemical Society, Washington (Stati Uniti d'America)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Ph. Lecle`re,*,+,? M. Surin,+ P. Viville,+ R. Lazzaroni,+ A. F. M. Kilbinger,§
O. Henze,§ W. J. Feast,§ M. Cavallini,| F. Biscarini,| A. P. H. J. Schenning,? and
E. W. Meijer? (literal)
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- ISI Web of Science (WOS) (literal)
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- 1. Univ Mons, Serv Chim Mat Nouveaux, B-7000 Mons, Belgium
2. Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
3. Univ Durham, IRC Polymer Sci & Technol, Durham DH1 3LE, England
4. ISMN, I-40129 Bologna, Italy (literal)
- Titolo
- About oligothiophene self-assembly: From aggregation in solution to solid-state nanostructures (literal)
- Abstract
- Well-defined pi-conjugated oligomers play an important role in the field of organic electronics, because their precise chemical structure and conjugation length give rise to well-defined functional properties and facilitate control over their supramolecular organization. In this review, we present different complementary approaches for the control of molecular assembly into well-defined structures on the nanoscale, applied to oligothiophenes as a typical conjugated system. We consider self-assembly in solution, sublimation of individual molecules in the vapor phase, and aggregation in thin deposits from compounds molecularly dispersed in a solution. We demonstrate that the development of substituted, soluble pi-conjugated materials allows not only a control of their organization in the solid state but also the possibility of determining the degree of order in solution. During these self-assembly processes, the interplay between the conjugated molecules, the solvent, and the substrate surface is of primary importance. Depending on the interactions between the molecules and the substrate, one-dimensional (nanowires) or two-dimensional (platelets) objects can be generated. The self-organization of conjugated building blocks in solution or on surfaces, leading to the construction of nanoscopic and mesoscopic architectures, represents a starting point for the construction of molecular electronics or even circuits, through surface patterning with nanometer-sized objects. (literal)
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