An umpolung sulfoxide reagent for use as a functionalized benzyl carbanion equivalent (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• An umpolung sulfoxide reagent for use as a functionalized benzyl carbanion equivalent (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.tet.2011.05.033 (literal)

Alternative label

• Pinna, Giovanni; Bellucci, Maria Cristina; Malpezzi, Luciana; Pisani, Laura; Superchi, Stefano; Volonterio, Alessandro; Zanda, Matteo (2011)
  An umpolung sulfoxide reagent for use as a functionalized benzyl carbanion equivalent
  in Tetrahedron (Oxf., Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Pinna, Giovanni; Bellucci, Maria Cristina; Malpezzi, Luciana; Pisani, Laura; Superchi, Stefano; Volonterio, Alessandro; Zanda, Matteo (literal)

Pagina inizio

• 5268 (literal)

Pagina fine

• 5281 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 67 (literal)

Rivista

• Tetrahedron (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 14 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 29 (literal)

Note

• ISI Web of Science (WoS) (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Polytechnic University of Milan; University of Milan; University of Basilicata; CNR ICRM; University of Aberdeen (literal)

Titolo

• An umpolung sulfoxide reagent for use as a functionalized benzyl carbanion equivalent (literal)

Abstract

• N-Methyl ortho-carbamoylaryl benzyl sulfoxides can be used as synthetic equivalents for alpha-hydroxy, alpha-chloro, and alpha-acetammido benzyl carbanions by means of a two-step sequence involving highly diastereoselective alpha-C-alkylation with alkyl halides followed by displacement of the sulfinyl residue (which can be recovered and recycled) by a hydroxyl, a chlorine or an acetamido, respectively, under non-oxidative Pummerer conditions. The scope and limits of the method, including a stereoselective version of the reaction, as well as the mechanism of the process are discussed in detail. (C) 2011 Elsevier Ltd. All rights reserved. (literal)

Prodotto di

• Targeting e inibizione dell'angiogenesi per la terapia anti-cancro (PM.P01.021.004) (Modulo)
• Istituto di chimica del riconoscimento molecolare (ICRM) (Istituto)

Autore CNR

• MATTEO ZANDA (Persona)
• ALESSANDRO VOLONTERIO (Persona)

Insieme di parole chiave

• Keywords of "An umpolung sulfoxide reagent for use as a functionalized benzyl carbanion equivalent" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• MATTEO ZANDA (Persona)
• ALESSANDRO VOLONTERIO (Persona)

Prodotto

• Istituto di chimica del riconoscimento molecolare (ICRM) (Istituto)
• Targeting e inibizione dell'angiogenesi per la terapia anti-cancro (PM.P01.021.004) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Tetrahedron (Rivista)

Insieme di parole chiave di

• Keywords of "An umpolung sulfoxide reagent for use as a functionalized benzyl carbanion equivalent" (Insieme di parole chiave)