Thermal and catalytic decomposition of wood impregnated with phosphorous- and sulfur-containing ammonium salts (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Thermal and catalytic decomposition of wood impregnated with phosphorous- and sulfur-containing ammonium salts (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.polymdegradstab.2007.12.003 (literal)

Alternative label

• C. Di Blasi; C. Branca; A. Galgano (2008)
  Thermal and catalytic decomposition of wood impregnated with phosphorous- and sulfur-containing ammonium salts
  in Polymer degradation and stability
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• C. Di Blasi; C. Branca; A. Galgano (literal)

Pagina inizio

• 335 (literal)

Pagina fine

• 346 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.elsevier.com/locate/polydegstab (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 93 (literal)

Rivista

• Polymer degradation and stability (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 12 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dipartimento di Ingegneria Chimica, Universita? degli Studi di Napoli \"Federico II\", P.le V. Tecchio, 80125 Napoli, Italy (literal)

Titolo

• Thermal and catalytic decomposition of wood impregnated with phosphorous- and sulfur-containing ammonium salts (literal)

Abstract

• The decomposition of fir wood, impregnated with diammonium sulfate and diammonium phosphate, has been investigated with a laboratory scale reactor together with gas-chromatographic analysis of gas and condensable organics. The dependence of products and other process variables on the salt concentration in the wood (from 0 to about 20% on a dry wood basis) and the heating temperature (650e900 K) is qualitatively similar for the two cases. Given heating temperatures of about 650e750 K and using as a reference water-extracted wood, diammonium sulfate and diammonium phosphate concentrations of about 1% are apt to cause a small increase (factors of 1.2e2) in the yields of levoglucosan, 5-methyl-2-furaldehyde and 2-acetylfuran, whereas values in the range 2e5% highly augment the yields of levoglucosenone and 2-furaldehyde (factors of 14e16 and 3e2, respectively). Salt concentrations above 10% confer excellent fire retardance properties of wood with total yields of water and char up to about 70 and 85% and ratio values of non-combustible to combustible volatile products up to 3.5 and 6.5, respectively. The displacement of the reaction process at lower temperatures, the higher exothermicity associated with the enhanced char formation, the reduced convective cooling and the endothermicity of salt decomposition also highly affect the conversion times and the overall rates of volatile species release. (literal)

Prodotto di

• Istituto di ricerche sulla combustione (IRC) (Istituto)
• Sviluppo di processi e tecnologie di trasformazione di fonti rinnovabili per la produzione di energia e materiali (ET.P03.002.002) (Modulo)

Autore CNR

• CARMEN BRANCA (Unità di personale interno)
• ANTONIO GALGANO (Persona)

Insieme di parole chiave

• Parole chiave di "Thermal and catalytic decomposition of wood impregnated with phosphorous- and sulfur-containing ammonium salts" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di ricerche sulla combustione (IRC) (Istituto)
• Sviluppo di processi e tecnologie di trasformazione di fonti rinnovabili per la produzione di energia e materiali (ET.P03.002.002) (Modulo)

Autore CNR di

• ANTONIO GALGANO (Persona)
• CARMEN BRANCA (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Polymer degradation and stability (Rivista)

Insieme di parole chiave di

• Parole chiave di "Thermal and catalytic decomposition of wood impregnated with phosphorous- and sulfur-containing ammonium salts" (Insieme di parole chiave)