Unexpected behavior of the surface composition of PtRh alloys during chemical reaction (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Unexpected behavior of the surface composition of PtRh alloys during chemical reaction (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ja044372+ (literal)

Alternative label

• A. Baraldi (1,2,3), D. Giacomello (1), L. Rumiz (4), M. Moretuzzo (1), S. Lizzit (4), F.Buatier de Mongeot (5), G. Paolucci (4), G. Comelli (1,2,3), R. Rosei (1,2,3), B.E. Nieuwenhuys (6), U. Valbusa (5), M.P. Kiskinova (4) (2005)
  Unexpected behavior of the surface composition of PtRh alloys during chemical reaction
  in Journal of the American Chemical Society (Print); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• A. Baraldi (1,2,3), D. Giacomello (1), L. Rumiz (4), M. Moretuzzo (1), S. Lizzit (4), F.Buatier de Mongeot (5), G. Paolucci (4), G. Comelli (1,2,3), R. Rosei (1,2,3), B.E. Nieuwenhuys (6), U. Valbusa (5), M.P. Kiskinova (4) (literal)

Pagina inizio

• 5671 (literal)

Pagina fine

• 5674 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 127 (literal)

Rivista

• Journal of the American Chemical Society (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 15 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopus (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• (1) Dipartimento di Fisica, UniVersita` di Trieste, Via Valerio 2, 34127 Trieste, Italy; (2) Laboratorio TASC-INFM, S.S. 14 Km 163.5, 34012 Trieste, Italy; (3) CENMAT Center of Excellence for Nanostructured Materials, Via Valerio 2, 34127, Trieste, Italy; (4) Sincrotrone Trieste S.C.p.A., S.S. 14 Km 163.5, 34012 Trieste, Italy; (5) INFM Unità di Genova and Dipartimento di Fisica, Via Dodecaneso 33, I-16146 Genova, Italy; (6) Leiden Institute of Chemistry, Leiden UniVersity, NL-2300 RA Leiden, The Netherlands (literal)

Titolo

• Unexpected behavior of the surface composition of PtRh alloys during chemical reaction (literal)

Abstract

• The changes in the surface composition of a Pt50Rh50(100) alloy due to an ongoing 2H(2) + O-2-2H(2)O chemical reaction have been studied in situ. Exploiting the high-energy resolution and surface sensitivity of synchrotron radiation core-level spectroscopy it was possible to monitor the population of the two transitions metals atoms at the gas-surface interface. Sequences of fast high-resolution core-level spectra of the Rh3d(5/2), Pt4f(7/2), and O1s core levels showed a continuous exchange of atoms between the first and subsurface layers. An unexpected Pt surface enrichement was found under slightly oxidizing conditions, opposite to what found in a highly oxidizing atmosphere. (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• MD.P06.016.001 Proprieta' elettroniche e strutturali di sistemi a bassa dimensionalita' (MD.P06.016.003) (Modulo)

Autore CNR

• ALESSANDRO BARALDI (Unità di personale esterno)
• GIOVANNI COMELLI (Persona)

Insieme di parole chiave

• Parole chiave di "Unexpected behavior of the surface composition of PtRh alloys during chemical reaction" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• ALESSANDRO BARALDI (Unità di personale esterno)
• GIOVANNI COMELLI (Persona)

Prodotto

• MD.P06.016.001 Proprieta' elettroniche e strutturali di sistemi a bassa dimensionalita' (MD.P06.016.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of the American Chemical Society (Rivista)

Editore di

• ACS, American chemical society (Editore)

Insieme di parole chiave di

• Parole chiave di "Unexpected behavior of the surface composition of PtRh alloys during chemical reaction" (Insieme di parole chiave)