http://www.cnr.it/ontology/cnr/individuo/prodotto/ID175449
Substrate Influence for the Zn-tetraphenyl-porphyrin Adsorption Geometry and the Interface-Induced Electron Transfer (Articolo in rivista)
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- Substrate Influence for the Zn-tetraphenyl-porphyrin Adsorption Geometry and the Interface-Induced Electron Transfer (Articolo in rivista) (literal)
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- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/cphc.201000017 (literal)
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Carla Castellarin-Cudia (1); Patrizia Borghetti (2); Giovanni Di Santo (1); Mattia Fanetti (1); Rosanna Larciprete (1,3); Cinzia Cepek (4); Paolo Vilmercati (1); Luigi Sangaletti (2); Alberto Verdini (4); Albano Cossaro (4); Luca Floreano (4); Alberto Morgante (4); Andrea Goldoni (1) (2010)
Substrate Influence for the Zn-tetraphenyl-porphyrin Adsorption Geometry and the Interface-Induced Electron Transfer
in ChemPhysChem (Print); Wiley-VCH Verlag Gmbh, Weinheim (Germania)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Carla Castellarin-Cudia (1); Patrizia Borghetti (2); Giovanni Di Santo (1); Mattia Fanetti (1); Rosanna Larciprete (1,3); Cinzia Cepek (4); Paolo Vilmercati (1); Luigi Sangaletti (2); Alberto Verdini (4); Albano Cossaro (4); Luca Floreano (4); Alberto Morgante (4); Andrea Goldoni (1) (literal)
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- http://onlinelibrary.wiley.com/doi/10.1002/cphc.201000017/abstract (literal)
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- [1] Sincrotrone Trieste S.C.p.A s.s. 14 km 163,5 in Area Science Park, 34149 Trieste (Italy)
[2] Dip. di Matematica e Fisica Universita' Cattolica del Sacro Cuore Via dei Musei 41, 25121 Brescia (Italy)
[3] CNR-Isituto dei Sistemi Complessi Via Fosso del Cavaliere 100, 00133 Roma (Italy)
[4] Laboratorio TASC, IOM-CNR s.s. 14 km 163,5 in Area Science Park, 34149 Trieste (Italy) (literal)
- Titolo
- Substrate Influence for the Zn-tetraphenyl-porphyrin Adsorption Geometry and the Interface-Induced Electron Transfer (literal)
- Abstract
- In molecular devices, the importance of interfaces cannot be neglected as they determine charge injection and charge flow and, therefore, the device performance. Herein we report on the interaction of one single layer of Zn-tetraphenyl-porphyrin with Ag(110) and Si(111). Photoemission, near-edge X-ray absorption, and resonant photoemission are used to study the bonding nature, the adsorption geometry as well as the dynamics of electron transfer between the molecules and the metal or semiconductor surfaces. Molecule-substrate charge transfer is driven by the overlap with the molecular ? orbitals. In particular, the coupling of the phenyl legs with the substrate and the relative excited charge injection are dramatically different for the two surfaces considered. (literal)
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