Comment on ''Local Methylthiolate Adsorption Geometry on Au(111) from Photoemission Core-Level Shifts'' (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Comment on ''Local Methylthiolate Adsorption Geometry on Au(111) from Photoemission Core-Level Shifts'' (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1103/PhysRevLett.103.119601 (literal)

Alternative label

• A. Cossaro; L. Floreano; A. Verdini; L. Casalis; A. Morgante (2009)
  Comment on ''Local Methylthiolate Adsorption Geometry on Au(111) from Photoemission Core-Level Shifts''
  in Physical review letters (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• A. Cossaro; L. Floreano; A. Verdini; L. Casalis; A. Morgante (literal)

Pagina inizio

• 119601 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 103 (literal)

Rivista

• Physical review letters (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 11 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1. INFM CNR, Lab TASC, Trieste, Italy 2. Sincrotrone Trieste SCpA, Trieste, Italy 3. Univ Trieste, Dept Phys, Trieste, Italy (literal)

Titolo

• Comment on ''Local Methylthiolate Adsorption Geometry on Au(111) from Photoemission Core-Level Shifts'' (literal)

Abstract

• We have investigated the controversy surrounding the (root 3x root 3)R30 degrees structure of self-assembled monolayers of methylthiolate on Au(111) by first principles molecular dynamics simulations, energy and angle resolved photoelectron diffraction, and grazing incidence x-ray diffraction. Our simulations find a dynamic equilibrium between bridge site adsorption and a novel structure where 2 CH3S radicals are bound to an Au adatom that has been lifted from the gold substrate. As a result, the interface is characterized by a large atomic roughness with both adatoms and vacancies. This result is confirmed by extensive photoelectron and grazing incidence x-ray diffraction measurements. (literal)

Prodotto di

• MD.P06.016.001 Proprieta' elettroniche e strutturali di sistemi a bassa dimensionalita' (MD.P06.016.003) (Modulo)

Autore CNR

• ALBERTO VERDINI (Unità di personale interno)
• ALBANO COSSARO (Persona)
• LUCA FLOREANO (Persona)
• ALBERTO MORGANTE (Unità di personale esterno)

Insieme di parole chiave

• Parole chiave di "Comment on ''Local Methylthiolate Adsorption Geometry on Au(111) from Photoemission Core-Level Shifts''" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• ALBANO COSSARO (Persona)
• LUCA FLOREANO (Persona)
• ALBERTO VERDINI (Unità di personale interno)
• ALBERTO MORGANTE (Unità di personale esterno)

Prodotto

• MD.P06.016.001 Proprieta' elettroniche e strutturali di sistemi a bassa dimensionalita' (MD.P06.016.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Physical review letters (Rivista)

Insieme di parole chiave di

• Parole chiave di "Comment on ''Local Methylthiolate Adsorption Geometry on Au(111) from Photoemission Core-Level Shifts''" (Insieme di parole chiave)