http://www.cnr.it/ontology/cnr/individuo/prodotto/ID174723
Filling empty states in a CuPc single layer on the Au(110) surface via electron injection (Articolo in rivista)
- Type
- Label
- Filling empty states in a CuPc single layer on the Au(110) surface via electron injection (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevB.79.115446 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- A. Calabrese; L. Floreano; A. Verdini; C. Mariani; M. G. Betti (literal)
- Pagina inizio
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- A. Calabrese; C. Mariani; M. G. Betti: Univ Roma La Sapienza, Dipartimento Fis, CNISM, I-00185 Rome, Italy
L. Floreano; A. Verdini: Lab Nazl TASC, INFM, CNR, I-34012 Trieste, Italy (literal)
- Titolo
- Filling empty states in a CuPc single layer on the Au(110) surface via electron injection (literal)
- Abstract
- An ordered copper-phthalocyanine (CuPc) single layer deposited on the Au(110) surface has been electron-doped by exposition to potassium. Progressive occupation of the former lowest unoccupied molecular orbitals (LUMOs) up to the filling of the twofold degenerate LUMO and LUMO+1 and LUMO+2 levels, has been detected by near-edge x-ray absorption spectroscopy spectra. The electronic states filled by electron transfer from the alkali atoms are localized at the interface, and the process induces a redistribution of the density of states with a conspicuous decrease in spectral density at the Fermi level. Localization of the final states, sudden decrease in density of states at the Fermi level, minor screening of the electron-hole excitations, and enhanced excitonic effects of doped CuPc with respect to the pristine CuPc single-layer concur to suggest that the electron injection produces a Mott insulator where correlation effects dominate the electronic propertie (literal)
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- Autore CNR
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