Metal-Directed Synthesis and Photophysical Studies of Trinuclear V-Shaped and Pentanuclear X-Shaped Ruthenium and Osmium Metallorods and Metallostars Based upon 4'-(3,5-Dihydroxyphenyl)-2,2':6',2''-terpyridine Divergent Units (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Metal-Directed Synthesis and Photophysical Studies of Trinuclear V-Shaped and Pentanuclear X-Shaped Ruthenium and Osmium Metallorods and Metallostars Based upon 4'-(3,5-Dihydroxyphenyl)-2,2':6',2''-terpyridine Divergent Units (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Alternative label

• Edwin C. Constable; Robyn W. Handel; Catherine E. Housecroft; Angeles Farran Morales; Barbara Ventura;Lucia Flamigni, Francesco Barigelletti (2005)
  Metal-Directed Synthesis and Photophysical Studies of Trinuclear V-Shaped and Pentanuclear X-Shaped Ruthenium and Osmium Metallorods and Metallostars Based upon 4'-(3,5-Dihydroxyphenyl)-2,2':6',2''-terpyridine Divergent Units
  in Chemistry (Weinh., Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Edwin C. Constable; Robyn W. Handel; Catherine E. Housecroft; Angeles Farran Morales; Barbara Ventura;Lucia Flamigni, Francesco Barigelletti (literal)

Pagina inizio

• 4024 (literal)

Pagina fine

• 4034 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 11 (literal)

Rivista

• Chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Department of Chemistry, University of Basel, Spitalstrasse 51, 4056 Basel (Switzerland) Istituto per la Sintesi Organica e Fotoreattivit? (ISOF-CNR) Via P. Gobetti 101, 40129 Bologna (Italy) (literal)

Titolo

• Metal-Directed Synthesis and Photophysical Studies of Trinuclear V-Shaped and Pentanuclear X-Shaped Ruthenium and Osmium Metallorods and Metallostars Based upon 4'-(3,5-Dihydroxyphenyl)-2,2':6',2''-terpyridine Divergent Units (literal)

Abstract

• A new series of V-shaped trinuclear metallorods and X-shaped pentanuclear metallostars has been prepared by the reaction of metal complexes bearing pendant phenolic functionalities with complexes containing electrophilic ligands. Specifically, {M- (tpy)2} motifs (M=Ru or Os; tpy= 2,2':6',2''-terpyridine) bearing one or two pendant 3,5-dihydroxyphenyl substituents at the 4-position of the central ring of the tpy have been reacted with the complexes [Ru(tpy)(Xtpy)]2+ (X= Cl or Br) to form new ether-linked species. The energy transfer from ruthenium to osmium in these complexes has been investigated in detail and the efficiency of transfer shown to be highly temperature dependent; the energy transfer is highly efficient at low temperature, whereas at room temperature nonradiative and nontransfer deactivation of the excited {Ru(tpy)2}* domains is most significant. (literal)

Prodotto di

• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Autore CNR

• BARBARA VENTURA (Persona)
• LUCIA FLAMIGNI (Unità di personale interno)
• FRANCESCO BARIGELLETTI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Metal-Directed Synthesis and Photophysical Studies of Trinuclear V-Shaped and Pentanuclear X-Shaped Ruthenium and Osmium Metallorods and Metallostars Based upon 4'-(3,5-Dihydroxyphenyl)-2,2':6',2''-terpyridine Divergent Units" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR di

• LUCIA FLAMIGNI (Unità di personale interno)
• FRANCESCO BARIGELLETTI (Unità di personale interno)
• BARBARA VENTURA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "Metal-Directed Synthesis and Photophysical Studies of Trinuclear V-Shaped and Pentanuclear X-Shaped Ruthenium and Osmium Metallorods and Metallostars Based upon 4'-(3,5-Dihydroxyphenyl)-2,2':6',2''-terpyridine Divergent Units" (Insieme di parole chiave)