Supported rhodium nanoparticles in catalysis: the role of stabilizers on catalytic activity and structural features (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Supported rhodium nanoparticles in catalysis: the role of stabilizers on catalytic activity and structural features (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/S0022-328X(03)00529-1 (literal)

Alternative label

• Vitulli G., Evangelisti C., Pertici P., Caporusso A.M., Panziera N., Salvadori P., Faga M.G., Manfredotti C., Martra G., Coluccia S., Balerna A., Colonna S., Mobilio S. (2003)
  Supported rhodium nanoparticles in catalysis: the role of stabilizers on catalytic activity and structural features
  in Journal of organometallic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Vitulli G., Evangelisti C., Pertici P., Caporusso A.M., Panziera N., Salvadori P., Faga M.G., Manfredotti C., Martra G., Coluccia S., Balerna A., Colonna S., Mobilio S. (literal)

Pagina inizio

• 37 (literal)

Pagina fine

• 50 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Excellent new generation hydrogenation, hydrosilylation and silylformilation catalysts, largely more active and selective than presently availables analogous commercial samples. (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 681 (literal)

Rivista

• Journal of organometallic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• Macrolinea ICCOM1 voce a - ICCOM - Sezione di Pisa (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#descrizioneSinteticaDelProdotto

• Rhodium nanoparticles supported on gamma-Al2O3, derived from arene-solvated Rh atoms stabilized by trioctylamine (TOA), are valuable catalysts in hydrogenation and silylformylation reactions. They are largely more active than the analogous commercial catalyst, as well as of a sample similarly prepared in the absence of TOA. HRTEM measurements, IR studies on adsorbed CO species and extended X-ray absorption fine structure analyses evidenced the role of TOA in controlling the particle growth in the preparative process and in stabilizing the resulting Rh particles against erosion by CO and oxidation. (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR-ICCOM - Sezione di Pisa; Dipartimento di Chimica e Chimica Industriale Università di Pisa; Dipartimento di Chimica I.F.M. Università di Torino; INFN-laboratori Nazionali di Frascati; CNR-Istituto di Struttura della Materia; Dipartimento di Fisica Università di Roma (literal)

Titolo

• Supported rhodium nanoparticles in catalysis: the role of stabilizers on catalytic activity and structural features (literal)

Abstract

• Rhodium nanoparticles supported on gamma-Al2O3, derived from arene-solvated Rh atoms stabilized by trioctylamine (TOA), are valuable catalysts in hydrogenation and silylformylation reactions. They are largely more active than the analogous commercial catalyst, as well as of a sample similarly prepared in the absence of TOA. HRTEM measurements, IR studies on adsorbed CO species and extended X-ray absorption fine structure analyses evidenced the role of TOA in controlling the particle growth in the preparative process and in stabilizing the resulting Rh particles against erosion by CO and oxidation. (literal)

Prodotto di

• Institute of structure of matter (ISM) (Istituto)
• Institute of science and technology for ceramics (ISTEC) (Istituto)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• STEFANO COLONNA (Persona)
• GIOVANNI VITULLI (Persona)
• PAOLO PERTICI (Persona)
• MARIA GIULIA FAGA (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Supported rhodium nanoparticles in catalysis: the role of stabilizers on catalytic activity and structural features" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of science and technology for ceramics (ISTEC) (Istituto)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Institute of structure of matter (ISM) (Istituto)

Autore CNR di

• GIOVANNI VITULLI (Persona)
• STEFANO COLONNA (Persona)
• PAOLO PERTICI (Persona)
• MARIA GIULIA FAGA (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of organometallic chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "Supported rhodium nanoparticles in catalysis: the role of stabilizers on catalytic activity and structural features" (Insieme di parole chiave)