http://www.cnr.it/ontology/cnr/individuo/prodotto/ID173056
Novel bifluorene based conjugated systems: synthesis and properties (Articolo in rivista)
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- Novel bifluorene based conjugated systems: synthesis and properties (Articolo in rivista) (literal)
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- 2006-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.tet.2005.10.010 (literal)
- Alternative label
Roberto Grisorio; Antonio Dell'Aquila; Giuseppe Romanazzi; Gian Paolo Suranna; Piero Mastrorilli; Pinalysa Cosma; Domenico Acierno; Eugenio Amendola; Giuseppe Ciccarella; and Cosimo Francesco Nobile (2006)
Novel bifluorene based conjugated systems: synthesis and properties
in Tetrahedron (Oxf., Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Roberto Grisorio; Antonio Dell'Aquila; Giuseppe Romanazzi; Gian Paolo Suranna; Piero Mastrorilli; Pinalysa Cosma; Domenico Acierno; Eugenio Amendola; Giuseppe Ciccarella; and Cosimo Francesco Nobile (literal)
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- ISI Web of Science (WOS) (literal)
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- Department of Water Engineering and Chemistry (DIAC), Polytechnic of Bari, via Orabona, 4 I-70125 Bari, Italy
Department of Civil and Enviromental Engineering (DICA), Polytechnic of Bari, via Orabona, 4 I-70125 Bari, Italy
Department of Chemistry, University of Bari, via Orabona 4, I-70125 Bari, Italy
Department of Materials and Production Engineering (DIMP), University of Naples Federico II, p.le Tecchio 80, I-80125 Naples, Italy
Institute of Composite and Biomedical Materials (IMCB), Italys National Research Council, p.le Tecchio 80, I-80125 Naples, Italy
Dipartimento di Ingegneria dellInnovazione, University of Lecce, Via Monteroni, I-73100 Lecce, Italy (literal)
- Titolo
- Novel bifluorene based conjugated systems: synthesis and properties (literal)
- Abstract
- A series of novel bifluorene based systems was synthesised by a convergent approach by means of a Suzuki cross-coupling
between 7,70-bis-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-9,9,90,90-tetraoctyl-2,20-bifluorene and suitable aryl-bromides. All the
oligomers have been characterized by 1H, 13C NMR, FT-IR, UVvis, PL spectroscopy and mass analyses. In particular, it has been
demonstrated that the presence of strong electron donor (amines) or withdrawing (carboxylic esters) groups causes a bathochromic shift of
the optical properties with respect to those of unsubstituted molecules. The effects of these functional groups on the HOMOLUMO energy
levels were investigated by cyclic voltammetry. Remarkably, the LUMO energy level of 7,70-bis-[50-carbodecaoxy-2,20-bithiophen-5-yl]-
9,9,90,90-tetraoctyl-2,20-bifluorene (K3.07 eV) is strongly influenced by the presence of the ester functional group. (literal)
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