http://www.cnr.it/ontology/cnr/individuo/prodotto/ID173001
Thermal and mechanical properties of simultaneous and sequential full-interpenetrating polymer networks (Articolo in rivista)
- Type
- Label
- Thermal and mechanical properties of simultaneous and sequential full-interpenetrating polymer networks (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.msea.2003.07.017 (literal)
- Alternative label
G. Di Marco; A. Bartolotta; M. Lanza, G. Carini; G. DAngelo, G. Tripodo; A. Fainleib; I. Danilenko; V. Grytsenko, L Sergeeva (2004)
Thermal and mechanical properties of simultaneous and sequential full-interpenetrating polymer networks
in Materials science & engineering. A, Structural materials: properties, microstructure and processing
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- G. Di Marco; A. Bartolotta; M. Lanza, G. Carini; G. DAngelo, G. Tripodo; A. Fainleib; I. Danilenko; V. Grytsenko, L Sergeeva (literal)
- Pagina inizio
- Pagina fine
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- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- - C.N.R., Istituto per i Processi Chimico-Fisici, sez. di Messina,Via La Farina 237, I-98123 Messina, Italy
- Dipartimento di Fisica and INFM, Universita di Messina, Salita Sperone 31, I-98166, S. Agata (ME), Italy
- Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, 02160 Kyiv, Ukraine (literal)
- Titolo
- Thermal and mechanical properties of simultaneous and sequential full-interpenetrating polymer networks (literal)
- Abstract
- An investigation of the thermal and mechanical characteristics of new full-interpenetrating polymer networks (full-IPNs), prepared by
simultaneous and sequential synthesis paths, has been performed in the temperature regions above and below the glass transition. It has
been observed that simultaneous full-IPNs exhibit higher values of density than sequential full-IPNs, as a consequence of an enhanced
intermolecular packing. This peculiarity leads to an increase of the glass transition temperature and to a larger gamma-suppression effect for
the gamma2-relaxation characterizing the polycyanurate phase of simultaneous full-IPNs, which has been ascribed to reduction of the free-volume
available for the molecular group rearrangements. (literal)
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