The mechanism of the Fischer-Tropsch reaction over supported cobalt catalysts (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• The mechanism of the Fischer-Tropsch reaction over supported cobalt catalysts (Articolo in rivista) (literal)

Anno

• 2010-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.molcata.2010.09.014 (literal)

Alternative label

• Kollár M. 1; De Stefanis A. 2; Solt H.E. 1; Mihályi M.R. 1; Valyon J. 1; Tomlinson A.A.G. 3 (2010)
  The mechanism of the Fischer-Tropsch reaction over supported cobalt catalysts
  in Journal of molecular catalysis. A, Chemical (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Kollár M. 1; De Stefanis A. 2; Solt H.E. 1; Mihályi M.R. 1; Valyon J. 1; Tomlinson A.A.G. 3 (literal)

Pagina inizio

• 37 (literal)

Pagina fine

• 45 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 333 (literal)

Rivista

• Journal of molecular catalysis. A, Chemical (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• http://dx.doi.org/10.1016/j.molcata.2010.09.014 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 9 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1-2 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1) Institute of Nanochemistry and Catalysis, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, Budapest 1025, Hungary 2) Institute for Inorganic Methodologies and Plasma (IMIP)-CNR, Rome Research Area-CNR, Via Salaria Km 29,300, Monterotondo, (Rome) 00016, Italy 3) Institute for the Structure of Matter (ISM)-CN, Rome Research Area-CNR, Via Salaria Km 29,300, Monterotondo, (Rome) 00016, Italy (literal)

Titolo

• The mechanism of the Fischer-Tropsch reaction over supported cobalt catalysts (literal)

Abstract

• Natural gas and coal are converted to fuels by the Fischer–Tropsch reaction, i.e., by reacting CO with H2, the currently accepted mechanism involving surface carbide formation. We have monitored the adsorbed species and their evolution during Fischer–Tropsch reaction on the commercial catalyst Pt,Co/gamma-Al2O3 (as a standard), on Co/alumina-pillared montmorillonite (Co,Al-EFW) and its beidellite analogue (both are tri-octahedral smectite clays, but beidellite possesses tetrahedrally coordinated Al in the sheets) via optical diffuse reflectance (DRS) and variable temperature in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). We show that in this case over Pt/Co-gamma-Al2O3, under model conditions, H2 reacts with CO forming H–C=O bridges over [Co-miO2-Co] units; this transition state moiety also involves adjacent matrix Al–O–CO units. Subsequent stages provide differing oxygenate species via concerted acid–base reactions. The early stages of the Fischer–Tropsch synthesis thus do not involve surface carbide species and surface oxygenates are generated via concerted reaction of support surface Al-OH with the above HCO-bridging binuclear Co2+ unit. (literal)

Prodotto di

• Institute of structure of matter (ISM) (Istituto)
• Dinamica dei processi atomici e molecolari (MD.P03.026.001) (Modulo)
• Nanostrutture metalliche e di ossidi (MD.P04.003.004) (Modulo)
• Istituto di Nanotecnologia (NANOTEC) (Istituto)

Autore CNR

• ANTHONY ARTHUR TOMLINSON (Persona)
• ADRIANA DE STEFANIS (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di Nanotecnologia (NANOTEC) (Istituto)
• Institute of structure of matter (ISM) (Istituto)
• Nanostrutture metalliche e di ossidi (MD.P04.003.004) (Modulo)
• Dinamica dei processi atomici e molecolari (MD.P03.026.001) (Modulo)

Autore CNR di

• ADRIANA DE STEFANIS (Unità di personale interno)
• ANTHONY ARTHUR TOMLINSON (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of molecular catalysis. A, Chemical (Rivista)