The Role of Triphenylamine in the Stabilization of Highly Efficient Polyfluorene-Based OLEDs: A Model Oligomers Study (Articolo in rivista)

Type
Label
  • The Role of Triphenylamine in the Stabilization of Highly Efficient Polyfluorene-Based OLEDs: A Model Oligomers Study (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/cphc.200900260 (literal)
Alternative label
  • Pasini, M.; Giovanella, U.; Betti, P.; Bolognesi, A., Botta, C.; Destri, S.; Porzio, W., Vercelli, B.; Zotti, G. (2009)
    The Role of Triphenylamine in the Stabilization of Highly Efficient Polyfluorene-Based OLEDs: A Model Oligomers Study
    in ChemPhysChem (Print); WILEY-V C H VERLAG GMBH, WEINHEIM (Germania)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Pasini, M.; Giovanella, U.; Betti, P.; Bolognesi, A., Botta, C.; Destri, S.; Porzio, W., Vercelli, B.; Zotti, G. (literal)
Pagina inizio
  • 2143 (literal)
Pagina fine
  • 2149 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://onlinelibrary.wiley.com/doi/10.1002/cphc.200900260/abstract;jsessionid=8466DC5AA1B7CDA136795561A51EF289.d01t01 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 10 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 12 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Pasini M., Giovanella U., Betti P., Bolognesi A., Botta C., Destri S., Porzio W., Istituto CNR per lo Studio delle Macromolecole, Via E. Bassini 15, 20133 Milano, Italy Zotti G., Vercelli B., Istituto CNR per l’ Energetica e le Interfasi, c.o Stati Uniti 4, 35127 Padova, Italy (literal)
Titolo
  • The Role of Triphenylamine in the Stabilization of Highly Efficient Polyfluorene-Based OLEDs: A Model Oligomers Study (literal)
Abstract
  • In order to understand the factors responsible for the improved efficiency and stability of organic light-emitting diodes (OLEDs) based on poly(9,9-dioctylfluorene) (PFO) when triphenylamine (TPA) is introduced as lateral fluorene substituent, we synthetize mono-disperse fluorene–thiophene oligomers as model compounds. Their blends with different concentrations of the fluorenone containing oligomer are studied in order to verify if only a reduction of ketonic defect sites or also an impeded energy transfer (ET) towards such sites are responsible for the suppression of the green emission band. We show that the introduction of TPA groups leads specifically both to an antioxidant action and a reduced ET towards residual defect sites, thanks to the environmental micro-encapsulation role played by TPA units surrounding the polymer backbone. As a result, the performances and colour stability of a device fabricated with TPA-substituted PFO (PFTPA) are strongly improved with respect to standard PFO device prepared in the same conditions. (literal)
Editore
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Autore CNR di
Prodotto
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Editore di
Insieme di parole chiave di
data.CNR.it