Synthesis, structure and butadiene polymerization behavior of CoCl2(PRxPh3-x)2 (R=methyl, ethyl, propyl, allyl, isopropyl, cyclohexyl; x=1,2). Influence of the phosphorous ligand on polymerization stereoselectivity (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Synthesis, structure and butadiene polymerization behavior of CoCl2(PRxPh3-x)2 (R=methyl, ethyl, propyl, allyl, isopropyl, cyclohexyl; x=1,2). Influence of the phosphorous ligand on polymerization stereoselectivity (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.jorganchem.2005.02.012 (literal)

Alternative label

• Ricci G.; Forni A.; Boglia A.; Sommazzi A.; Masi F. (2005)
  Synthesis, structure and butadiene polymerization behavior of CoCl2(PRxPh3-x)2 (R=methyl, ethyl, propyl, allyl, isopropyl, cyclohexyl; x=1,2). Influence of the phosphorous ligand on polymerization stereoselectivity
  in Journal of organometallic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Ricci G.; Forni A.; Boglia A.; Sommazzi A.; Masi F. (literal)

Pagina inizio

• 1845 (literal)

Pagina fine

• 1854 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://ac.els-cdn.com/S0022328X05001300/1-s2.0-S0022328X05001300-main.pdf?_tid=63278c8292bb286f767a401a3c05a1c8&acdnat=1335441249_537550bcfa645ee3a7b86cb2f91a41be (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 690 (literal)

Rivista

• Journal of organometallic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 7 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• G. Ricci, A. Boglia,:ISMAC CNR Milano A. Forni,: ISTM CNR Milano A. Sommazzi,: Polimeri Europa Novara F. Masi,: Polimeri Europa Milano (literal)

Titolo

• Synthesis, structure and butadiene polymerization behavior of CoCl2(PRxPh3-x)2 (R=methyl, ethyl, propyl, allyl, isopropyl, cyclohexyl; x=1,2). Influence of the phosphorous ligand on polymerization stereoselectivity (literal)

Abstract

• Several cobalt(II) phosphine complexes have been synthesized by reacting cobalt(II) chloride with various mono- and diphenylalkylphosphines (PRxPh3?x; R = methyl, ethyl, allyl, propyl, isopropyl, cyclohexyl; x = 1, 2). For some of these complexes single crystals were obtained and their molecular structures were determined by X-ray diffraction method. All the complexes were then used in association with MAO for the polymerization of 1,3-butadiene and they were found to be extremely active. Predominantly 1,2 polymers having different tacticity (predominantly iso- or syndiotactic), depending on the type of phosphine ligand bonded to the cobalt atom, were obtained. An interpretation of this particular behavior, based on the diene polymerization mechanism previously proposed, is reported. (literal)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Nanoingegneria chimica di sistemi assemblati mediante interazioni intermolecolari specifiche (PM.P07.002.002) (Modulo)
• Catalisi per nuove architetture macromolecolari e sistemi polimerici nanostrutturati e biomimetici (PM.P02.005.003) (Modulo)

Autore CNR

• ALDO BOGLIA (Persona)
• GIOVANNI RICCI (Persona)
• ALESSANDRA FORNI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Synthesis, structure and butadiene polymerization behavior of CoCl2(PRxPh3-x)2 (R=methyl, ethyl, propyl, allyl, isopropyl, cyclohexyl; x=1,2). Influence of the phosphorous ligand on polymerization stereoselectivity" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Catalisi per nuove architetture macromolecolari e sistemi polimerici nanostrutturati e biomimetici (PM.P02.005.003) (Modulo)
• Nanoingegneria chimica di sistemi assemblati mediante interazioni intermolecolari specifiche (PM.P07.002.002) (Modulo)

Autore CNR di

• ALDO BOGLIA (Persona)
• GIOVANNI RICCI (Persona)
• ALESSANDRA FORNI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of organometallic chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "Synthesis, structure and butadiene polymerization behavior of CoCl2(PRxPh3-x)2 (R=methyl, ethyl, propyl, allyl, isopropyl, cyclohexyl; x=1,2). Influence of the phosphorous ligand on polymerization stereoselectivity" (Insieme di parole chiave)