Reactivity of Tris(1-pyrazolyl)methane Towards Ru0 Complexes (Articolo in rivista)

Type
Label
  • Reactivity of Tris(1-pyrazolyl)methane Towards Ru0 Complexes (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/ejic.201100382 (literal)
Alternative label
  • Guelfi, Massimo; Calucci, Lucia; Forte, Claudia; Pertici, Paolo; Denti, Gianfranco (2011)
    Reactivity of Tris(1-pyrazolyl)methane Towards Ru0 Complexes
    in European journal of inorganic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Guelfi, Massimo; Calucci, Lucia; Forte, Claudia; Pertici, Paolo; Denti, Gianfranco (literal)
Pagina inizio
  • 3529 (literal)
Pagina fine
  • 3533 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 23 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Universit√† di Pisa, Facolt√† di Agraria, Inorganic Chemistry Laboratory, I-56124 Pisa, Italy CNR Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti OrganoMetallici, Area della Ricerca di Pisa, I-56124 Pisa, Italy (literal)
Titolo
  • Reactivity of Tris(1-pyrazolyl)methane Towards Ru0 Complexes (literal)
Abstract
  • By treating tris(1-pyrazolyl)methane (tpm) with suitably activated [Ru(cod)(cot)] and [Ru(cod)(nap)] (cod = eta(4)-cycloocta-1,5-diene, cot = eta(6)-cycloocta-1,3,5-triene, nap = eta(6)-naphthalene) the (hydrido)Ru-II species [Ru(N-2,N-2',C-5\"tpm)(cod)H] with cyclometalated tpm was obtained. This complex reacted with chloroform at room temperature to give [Ru(N-2,N-2',C-5\"tpm)(cod)Cl] and dichloromethane. The coordination and symmetry of the novel complexes were elucidated by H-1 and C-13 NMR spectroscopy. (literal)
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