Gas-phase complexes: noncovalent interactions and stereospecificity (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Gas-phase complexes: noncovalent interactions and stereospecificity (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Alternative label

• D. Scuderi, A. Paladini, M. Satta, D. Catone, A. Filippi, S. Piccirillo, A. Lagana, M. Speranza, A. Giardini Guidoni (2003)
  Gas-phase complexes: noncovalent interactions and stereospecificity
  in International journal of mass spectrometry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• D. Scuderi, A. Paladini, M. Satta, D. Catone, A. Filippi, S. Piccirillo, A. Lagana, M. Speranza, A. Giardini Guidoni (literal)

Pagina inizio

• 159 (literal)

Pagina fine

• 168 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 223 (literal)

Rivista

• International journal of mass spectrometry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ISM - Istituto di Struttura della Materia (literal)

Titolo

• Gas-phase complexes: noncovalent interactions and stereospecificity (literal)

Abstract

• Chiral recognition is a fundamental phenomenon in life sciences based on the enantioselective complexation of a chiral molecule with a chiral selector. The diastereomeric aggregates, formed by complexation, are held together by a different combination of intermolecular forces and are, therefore, endowed with different stability and reactivity. Determination of these forces, which are normally affected in the condensed phase by solvent and supramolecular interactions, requires the generation of the diastereomeric complexes in an isolated state and their kinetic and spectroscopic investigation. This paper concerns enantiodiscrimination of chiral molecules in the gas phase through the application of various ESI-MSn-CID and REMPI-TOF methodologies. The measurement of the fragmentation thresholds of diastereomeric clusters by these techniques allowed to shed light upon the nature and the magnitude of the intrinsic interactions which control their formation and which affect their stability and reactivity. (literal)

Prodotto di

• Interazione Laser Materia (MD.P03.030.001) (Modulo)
• Istituto di Nanotecnologia (NANOTEC) (Istituto)
• Superfici Funzionalizzate, Interfacce, Riconoscimento Molecolare e Catalisi (MD.P06.005.001) (Modulo)
• Institute of structure of matter (ISM) (Istituto)

Autore CNR

• MAURO SATTA (Persona)
• DANIELE CATONE (Unità di personale interno)
• ANNA GIARDINI (Persona)

Incoming links:

Prodotto

• Istituto di Nanotecnologia (NANOTEC) (Istituto)
• Institute of structure of matter (ISM) (Istituto)
• Superfici Funzionalizzate, Interfacce, Riconoscimento Molecolare e Catalisi (MD.P06.005.001) (Modulo)
• Interazione Laser Materia (MD.P03.030.001) (Modulo)

Autore CNR di

• MAURO SATTA (Persona)
• ANNA GIARDINI (Persona)
• DANIELE CATONE (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• International journal of mass spectrometry (Rivista)