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Adsorption layer characteristics of Tritons surfactants 3. Dilational visco-elasticity (Articolo in rivista)
- Type
- Label
- Adsorption layer characteristics of Tritons surfactants 3. Dilational visco-elasticity (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.colsurfa.2008.10.042 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- V.B. Fainerman; E.V. Aksenenko; S.V. Lylyk; A.V. Makievski; F. Ravera; J.T. Petkov; J. Yorke; R. Miller (literal)
- Pagina inizio
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
- In: Colloids and Surfaces A-Physicochemical and Engineering Aspects, vol. 334 (1-3) pp. 16 - 21. Elsevier, 2009. (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- ISI Web of Science (WOS) (literal)
- Scopu (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Medical Physicochemical Centre, Donetsk Medical University, Donetsk, Ukraine,
Institute of Colloid Chemistry and Chemistry of Water, Kyiv (Kiev), Ukraine,
SINTERFACE Technologies, Berlin, Germany,
CNR-IENI, Genova, Italy
Unilever R&D, Bebington, UK,
Max-Planck-Institut für Kolloid- und Grenzflächenforschung, Potsdam, Germany (literal)
- Titolo
- Adsorption layer characteristics of Tritons surfactants 3. Dilational visco-elasticity (literal)
- Abstract
- The dilational rheology of adsorption layers of four Tritons (TX45. TX100, TX165 and TX405) was studied by using the oscillating drop and bubble profile methods at frequencies between 0.005 Hz and 0.2 Hz. It is shown that the visco-elasticity modulus |E| for TX45 solutions can be excellently described by a rigorous reorientation model. For the description of the dilational rheology of TX100 adsorption layers an additional compressibility of the adsorbed molecules at high Surface pressure has to be considered. Also the phase angle phi as a function of concentration can be described quantitatively for the two Tritons. For TX165 and TX405, having a much larger number of ethylene oxide units, the models is not in good agreement with the experimental data. For these molecules, obviously the presence of homologues in the surfactant samples play a larger role and the dependencies of |E|(c) and phi(c) show features as common for surfactant mixtures. (C) 2008 Elsevier B.V. All rights reserved. (literal)
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