http://www.cnr.it/ontology/cnr/individuo/prodotto/ID17002
Highly fluorus zirconocene (IV) complexes and their catalytic applications in the polymerization of ethylene (Articolo in rivista)
- Type
- Label
- Highly fluorus zirconocene (IV) complexes and their catalytic applications in the polymerization of ethylene (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.jorganchem.2010.03.030 (literal)
- Alternative label
Cámpora J., Matas I., Pilar P., Álvarez E., Kleijn H., Deelman B., Passaglia E. (2010)
Highly fluorus zirconocene (IV) complexes and their catalytic applications in the polymerization of ethylene
in Journal of organometallic chemistry (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Cámpora J., Matas I., Pilar P., Álvarez E., Kleijn H., Deelman B., Passaglia E. (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Instituto de Investigaciones Químicas, Consejo Superior de Investigaciones Científicas, Universidad de Sevilla, Avda. Américo Vespucio 49, 41092 Sevilla, Spain
Organic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Padualaan 8, NL-3584 CH Utrecht, The Netherlands
CNR-ICCOM UOS Pisa (literal)
- Titolo
- Highly fluorus zirconocene (IV) complexes and their catalytic applications in the polymerization of ethylene (literal)
- Abstract
- The catalytic activities of the highly fluorous systems formed by the zirconocene(IV) complexes [Zr{h5-
C5H4SiMe2C2H4RF}2Cl2] (RF ¼ C6F13 (4a), C10F21 (4b)) or [Zr-{h5-C5H3(SiMe2C2H4C6F13)2}2Cl2] (5a) and
MMAO in toluene have been studied and compared with analogous nonfluorous systems generated from
[Zr{h5-C5H4SiMe3}2Cl2] and [Zr{h5-C5H5}2Cl2]. Although less active than the reference systems, the fluorous
catalysts are stable over prolonged polymerization times, giving rise to polymers with similar
molecular weights to those obtained with [Zr{h5-C5H4SiMe3}2Cl2]. (literal)
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