A helical peptide receptor for [60]fullerene (Articolo in rivista)

Type
Label
  • A helical peptide receptor for [60]fullerene (Articolo in rivista) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/1521-3765(20020402)8:7<1544::AID-CHEM1544>3.0.CO;2-T (literal)
Alternative label
  • Bianco A., Corvaja C., Crisma M., Guldi D.M., Maggini M., Sartori E., Toniolo C. (2002)
    A helical peptide receptor for [60]fullerene
    in Chemistry (Weinh., Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bianco A., Corvaja C., Crisma M., Guldi D.M., Maggini M., Sartori E., Toniolo C. (literal)
Pagina inizio
  • 1544 (literal)
Pagina fine
  • 1553 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
  • Citazioni WOS: 13 Impact Factor 2002: 4.238 Coautore (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 8 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CSB-CNR and CMRO-CNR, Dipartimento di Chimica Organica, Università di Padova, 35131 Padova, Italy; Dipartimento di Chimica Fisica, Università di Padova, 35131 Padova, Italy; Radiation Laboratory, University of Notre Dame, Notre Dame, IN 46656, USA (literal)
Titolo
  • A helical peptide receptor for [60]fullerene (literal)
Abstract
  • Two nonapeptides, each made up of six Aib residues, a Gly spacer and two L-Tyr residues in positions 2 and 8 (these are substituted in the side chain with either ferrocenoyl or methyl moieties) have been synthesized. Solution conformational analyses (FT-IR and NMR) indicate that a 3-10-helical conformation is adopted by these rigid peptides in strucutre-supporting solvents. An X-ray diffraction investigation shows that the bis-L-Tyr(Me) nonapeptide in the crystal state is folded into a regular right-handed 3-10-helical structure. A detailed photophysical analysis provides evidence that the electron-rich, hydrophobic and wide cavity generated by the nonapeptide with two ferrocenoylbenzyl walls is able to host [60]fullerene. (literal)
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