Confined electrodeposition using a template-assisted procedure based on the selective (Articolo in rivista)

Type
Label
  • Confined electrodeposition using a template-assisted procedure based on the selective (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/la902506m (literal)
Alternative label
  • Foresti M. L., Loglio F., Innocenti M, Bellassai S., Carlà F., Lastraioli E., Pezzatini G., Bianchini C., Vizza F. (2010)
    Confined electrodeposition using a template-assisted procedure based on the selective
    in Langmuir
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Foresti M. L., Loglio F., Innocenti M, Bellassai S., Carlà F., Lastraioli E., Pezzatini G., Bianchini C., Vizza F. (literal)
Pagina inizio
  • 1802 (literal)
Pagina fine
  • 1806 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 26 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto di Chimica dei Composti Organometallici (ICCOM-CNR), via Madonna del Piano10, 50019 Sesto Fiorentino (FI), Italy; Department of Chemistry, University of Florence, Via della Lastruccia 3, 50019 Sesto Fiorentino (FI), Italy (literal)
Titolo
  • Confined electrodeposition using a template-assisted procedure based on the selective (literal)
Abstract
  • Confined electrodeposition can be achieved through the use of suitable templates, bywhich the electrodeposition occurs in natural or artificial holes of an insulating layer on a conducting substrate.Here, we present the electrodeposition of CdS on the holes left by the selective desorption of 3-mercaptopropionic acid (MPA) from a binary self-assembled monolayer (SAM) formed on Ag(111) with 1-octanethiol (OT). The electrodeposition of a compound is quite demanding, since it requires the right stoichiometry. In addition, the surface underpotential deposition phenomena exploited by electrochemical atomic layer epitaxy (ECALE) technique ensures that the surface available for electrodeposition after the selective desorption is still Ag(111). Parallel electrochemical experiments show that the amount of compound electrodeposited is consistent with this free Ag(111) surface, and the morphological analysis performed both by atomic force microscopy (AFM) and by lateral force microscopy (LFM) confirm the electrochemical data. (literal)
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