http://www.cnr.it/ontology/cnr/individuo/prodotto/ID16949
Fluorinated Poly(p-phenylenevinylene)s: Synthesis and Optical Properties of an Intriguing Class of Luminescent Polymers (Articolo in rivista)
- Type
- Label
- Fluorinated Poly(p-phenylenevinylene)s: Synthesis and Optical Properties of an Intriguing Class of Luminescent Polymers (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.3390/ma3053077 (literal)
- Alternative label
Farinola G. M., Cardone A., Babudri F., Martinelli C., Naso F., Bruno B., Losurdo M. (2010)
Fluorinated Poly(p-phenylenevinylene)s: Synthesis and Optical Properties of an Intriguing Class of Luminescent Polymers
in Materials (Basel); MDPI AG, Basel (Swaziland)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Farinola G. M., Cardone A., Babudri F., Martinelli C., Naso F., Bruno B., Losurdo M. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- Scopus (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Martinelli C., Naso F., Bruno B., Losurdo M. (literal)
- Titolo
- Fluorinated Poly(p-phenylenevinylene)s: Synthesis and Optical Properties of an Intriguing Class of Luminescent Polymers (literal)
- Abstract
- This review is an overview of our previous work on the synthesis and properties
of poly(p-phenylenevinylene)s (PPVs) selectively fluorinated in different positions of the
conjugated backbone. Both the synthetic challenges and the effects of functionalization with
fluorine atoms on the optical behavior are discussed, highlighting the peculiarities and the
interest of this class of conjugated polymers. A general polymerization protocol for PPVs,
that is based on the Pd-catalyzed Stille cross-coupling reaction of bis-stannylated vinylene
monomers with aromatic bis-halides, has been successfully extended to the synthesis of
selectively fluorinated poly(p-phenylenevinylene)s. The properties of a series of these PPVs
differing in the number and positions of the fluorine atoms on the conjugated backbone have
been studied, even in comparison with the non-fluorinated counterparts. The intriguing
optical features of the resulting materials are discussed considering not only the role of the
electronic and steric effects induced by the fluorine substituents, but also the impact of the
fluorination on the solid state organization and intermolecular interactions. (literal)
- Editore
- Prodotto di
- Autore CNR
Incoming links:
- Prodotto
- Autore CNR di
- Editore di
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi