A New Cobalt(II) Layered Network Based on Phenyl(carboxymethyl) phosphinate (Articolo in rivista)

Type
Label
  • A New Cobalt(II) Layered Network Based on Phenyl(carboxymethyl) phosphinate (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/ejic.201000276 (literal)
Alternative label
  • Costantino, Ferdinando; Ienco, Andrea; Midollini, Stefano; Orlandini, Annabella; Rossin, Andrea; Sorace, Lorenzo (2010)
    A New Cobalt(II) Layered Network Based on Phenyl(carboxymethyl) phosphinate
    in European journal of inorganic chemistry (Print); Wiley-VCH Verlag Gmbh, Weinheim (Germania)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Costantino, Ferdinando; Ienco, Andrea; Midollini, Stefano; Orlandini, Annabella; Rossin, Andrea; Sorace, Lorenzo (literal)
Pagina inizio
  • 3179 (literal)
Pagina fine
  • 3184 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, Ist Chim Composti Organomet, I-50019 Florence, Italy Univ Perugia, Dipartimento Chim & CEMIN, I-06123 Perugia, Italy Univ Firenze, UdR INSTM, I-50019 Florence, Italy Univ Firenze, Dipartimento Chim, I-50019 Florence, Italy (literal)
Titolo
  • A New Cobalt(II) Layered Network Based on Phenyl(carboxymethyl) phosphinate (literal)
Abstract
  • In the presence of 4,4'-bipyridine (4,4'-bipy) and Co(II) metal ions, a bifunctional phosphinate-carboxylate ligand, phenyl(carboxymethyl) phosphinate (pcc), forms a new polymeric metal-organic framework (MOF), [[Co(pcc)(4,4'-bipy)(H(2)O)]-(H(2)O)(1.5)](n) (1). The structure consists of 2D slabs connected by solvent water molecules with cobalt metal atoms in two different coordination environments. The temperature-dependent X-ray powder diffraction analysis of 1 shows the formation of dehydrated phases in the range 120-180 degrees C. The dehydration rehydration process is reversible. The overall magnetic behaviour of complex 1 is dominated by single ion effects with only weak exchange coupling interactions, due to the syn/anti conformation of the Co-O-C-O-Co path. (literal)
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