Selective s-Bond Metathesis in Alkyl-Aryl and Alkyl-Benzyl Yttrium Complexes. New Aryl- and Benzyl-Hydrido Yttrium Derivatives Supported by Amidopyridinate Ligands (Articolo in rivista)

Type
Label
  • Selective s-Bond Metathesis in Alkyl-Aryl and Alkyl-Benzyl Yttrium Complexes. New Aryl- and Benzyl-Hydrido Yttrium Derivatives Supported by Amidopyridinate Ligands (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/om801044h (literal)
Alternative label
  • Lyubov D. M., Fukin G. K., Cherkasov A. V., Shavyrin A. S., Trifonov A. A., Luconi L., Bianchini C., Meli A., Giambastiani G. (2009)
    Selective s-Bond Metathesis in Alkyl-Aryl and Alkyl-Benzyl Yttrium Complexes. New Aryl- and Benzyl-Hydrido Yttrium Derivatives Supported by Amidopyridinate Ligands
    in Organometallics (Online); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Lyubov D. M., Fukin G. K., Cherkasov A. V., Shavyrin A. S., Trifonov A. A., Luconi L., Bianchini C., Meli A., Giambastiani G. (literal)
Pagina inizio
  • 1227 (literal)
Pagina fine
  • 1232 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 28 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 6 (literal)
Note
  • Scopus (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • G. A. RazuVaeV Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, GSP-445, 603950 Nizhny NoVgorod, Russia, Istituto di Chimica dei Composti Organometallici (ICCOM - CNR), Via Madonna del Piano 10, 50019, Sesto Fiorentino, Italy (literal)
Titolo
  • Selective s-Bond Metathesis in Alkyl-Aryl and Alkyl-Benzyl Yttrium Complexes. New Aryl- and Benzyl-Hydrido Yttrium Derivatives Supported by Amidopyridinate Ligands (literal)
Abstract
  • Yttrium dialkyl complexes coordinated by 6-aryl-substituted amidopyridinate ligands undergo selective intramolecular sp2 or sp3 C-H bond activation. Upon treatment with PhSiH3 of the resulting Y-C(alkyl, aryl) or Y-C(alkyl,benzyl) systems, a ?-bond metathesis reaction takes place selectively at the Y-C(alkyl) bond, generating rare dimeric aryl-hydrido or benzyl-hydrido yttrium complexes, respectively. (literal)
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