Electrolytic loading of hydrogen in Zr65(Pd80Rh20)35 and Zr65Pd35 alloys prepared by mechanical grinding and in their oxidised derivatives (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Electrolytic loading of hydrogen in Zr65(Pd80Rh20)35 and Zr65Pd35 alloys prepared by mechanical grinding and in their oxidised derivatives (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.electacta.2007.04.119 (literal)

Alternative label

• Battagliarin M.; Comisso N.; Mengoli G.; Sitran S. (2007)
  Electrolytic loading of hydrogen in Zr65(Pd80Rh20)35 and Zr65Pd35 alloys prepared by mechanical grinding and in their oxidised derivatives
  in Electrochimica acta
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Battagliarin M.; Comisso N.; Mengoli G.; Sitran S. (literal)

Pagina inizio

• 6821 (literal)

Pagina fine

• 6833 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0013468607006251 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 52 (literal)

Rivista

• Electrochimica acta (Rivista)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1-3 : CNR IENI, Corso Stati Uniti 4, 35127 Padova, Italy 4 : CNR ICIS, Corso Stati Uniti 4, 35127 Padova, Italy (literal)

Titolo

• Electrolytic loading of hydrogen in Zr65(Pd80Rh20)35 and Zr65Pd35 alloys prepared by mechanical grinding and in their oxidised derivatives (literal)

Abstract

• Zr65(Pd80Rh20)35 and Zr65Pd35 alloys were prepared by mechanical grinding of stoichiometric amounts of either ZrH2 and Pd80Rh20 or ZrH2 and Pd. Following a suggestion in the literature, these alloys were converted by thermal oxidation in air into the corresponding ZrO2(Pd80Rh20) and ZrO2Pd compounds, which are probably composed of Pd80Rh20 and Pd nanostructures embedded in ZrO2. The aim of our work thereafter was to investigate hydrogen storage in these nanostructures. Both the alloys and their oxidation derivatives were thus loaded with hydrogen by cathodic reduction at 25°C in 6 M KOH, and loaded hydrogen was then determined by anodic extraction. On comparing the hydriding extent of the alloys with that of the corresponding oxidation derivatives, the metal clusters which formed after thermal oxidation are probably much larger in PdRh than in Pd. The former exhibits the high decomposition pressure typical of massive Pd80Rh20 hydride, and the maximum [H]/[Pd0.8Rh0.2] atom ratio is » 0.82. Conversely, the amount of hydrogen extracted from reduced ZrO2Pd samples prepared in optimal conditions fits [H]/[Pd] atom ratios between 1 and 2. The shape of the electrochemical hydrogen desorption isotherms indicates that the hydrogen in excess of the b–Pd hydride phase is probably stored in a new, very stable form. (literal)

Prodotto di

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Materiali e Processi per l'Elettrochimica dell'Idrogeno e l'Elettrocatalisi (ET.P06.011.001) (Modulo)
• MAteriali Funzionali Organici per applicazioni High-Tech: sistemi molecolari, supramolecolari e bioibridi (MAFO-HT) (PM.P04.003.002) (Modulo)
• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR

• GIULIANO MENGOLI (Unità di personale interno)
• NICOLA COMISSO (Unità di personale interno)
• SERGIO SITRAN (Unità di personale interno)
• MARINO BATTAGLIARIN (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Electrolytic loading of hydrogen in Zr65(Pd80Rh20)35 and Zr65Pd35 alloys prepared by mechanical grinding and in their oxidised derivatives" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• NICOLA COMISSO (Unità di personale interno)
• SERGIO SITRAN (Unità di personale interno)
• GIULIANO MENGOLI (Unità di personale interno)
• MARINO BATTAGLIARIN (Unità di personale interno)

Prodotto

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Materiali e Processi per l'Elettrochimica dell'Idrogeno e l'Elettrocatalisi (ET.P06.011.001) (Modulo)
• MAteriali Funzionali Organici per applicazioni High-Tech: sistemi molecolari, supramolecolari e bioibridi (MAFO-HT) (PM.P04.003.002) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Electrochimica acta (Rivista)

Insieme di parole chiave di

• Parole chiave di "Electrolytic loading of hydrogen in Zr65(Pd80Rh20)35 and Zr65Pd35 alloys prepared by mechanical grinding and in their oxidised derivatives" (Insieme di parole chiave)