Getting a clue to the hydrolytic activation of white phosphorus: the generation and stabilization of P(OH)2PHPHPH(OH) at ruthenium centers (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Getting a clue to the hydrolytic activation of white phosphorus: the generation and stabilization of P(OH)2PHPHPH(OH) at ruthenium centers (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ic801859z (literal)

Alternative label

• Barbaro, Pierluigi; Di Vaira, Massimo; Peruzzini, Maurizio; Seniori Costantini, Stefano; Stoppioni, Piero (2009)
  Getting a clue to the hydrolytic activation of white phosphorus: the generation and stabilization of P(OH)2PHPHPH(OH) at ruthenium centers
  in Inorganic chemistry
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Barbaro, Pierluigi; Di Vaira, Massimo; Peruzzini, Maurizio; Seniori Costantini, Stefano; Stoppioni, Piero (literal)

Pagina inizio

• 1091 (literal)

Pagina fine

• 1096 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 48 (literal)

Rivista

• Inorganic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM CNR, Via Madonna del Piano, 10, 50019, Sesto Fiorentino, Firenze, Italy. Dipartimento di Chimica, UniVersita` di Firenze, Via della Lastruccia, 3, 50019 Sesto Fiorentino, Firenze, Italy. (literal)

Titolo

• Getting a clue to the hydrolytic activation of white phosphorus: the generation and stabilization of P(OH)2PHPHPH(OH) at ruthenium centers (literal)

Abstract

• The bimetallic compound [{CpRu(PPh3)2}2(?,?1:1-P4)][CF3SO3]2, in which the tetrahedral P4 is bound to two CpRu(PPh3)2 fragments, slowly reacts under mild conditions with a moderate excess of water (1:20) to yield a mixture of compounds. Among the hydrolysis products, the new, remarkably stable complexes [{CpRu(PPh3)}{CpRu- (PPh3)2}{?1,4:3,?2:1-P(OH)2PHPHPH(OH)}](CF3SO3)2 (2) and [{CpRu(PPh3)2}{CpRu(PPh3){P(OH)3)}(?,?1:1-P2H4)]- (CF3SO3)2 (3) have been isolated. In the former, the previously unknown 1,1,4-tris(hydroxy)tetraphosphane molecule, P(OH)2PHPHPH(OH), is 1,4- and, respectively, 3-coordinated to the CpRu(PPh3) and the CpRu(PPh3)2 moieties; in the latter, the diphosphane P2H4 is stabilized through coordination to two different metal fragments. All of the compounds were characterized by elemental analyses and IR and NMR spectroscopy. The crystal structure of 2 was determined by X-ray analysis. The formation of the hydroxytetraphosphane, containing the tetraphosphorus entity, provides a clue to the hydrolytic activation of the P4 molecule. (literal)

Prodotto di

• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• Piero Stoppioni (Persona)
• PIERLUIGI BARBARO (Unità di personale interno)
• MAURIZIO PERUZZINI (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)

Autore CNR di

• PIERLUIGI BARBARO (Unità di personale interno)
• MAURIZIO PERUZZINI (Unità di personale interno)
• Piero Stoppioni (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry (Rivista)