Oxyfunctionalization of Non-Natural Targets by Dioxiranes. 6. On the Selective Hydroxylation of Cubane (Articolo in rivista)

Type
Label
  • Oxyfunctionalization of Non-Natural Targets by Dioxiranes. 6. On the Selective Hydroxylation of Cubane (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/ol901302d (literal)
Alternative label
  • Annese C.; D'Accolti L.; Fusco C.; Gandolfi R.; Eaton P. E.; Curci R. (2009)
    Oxyfunctionalization of Non-Natural Targets by Dioxiranes. 6. On the Selective Hydroxylation of Cubane
    in Organic letters (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Annese C.; D'Accolti L.; Fusco C.; Gandolfi R.; Eaton P. E.; Curci R. (literal)
Pagina inizio
  • 3574 (literal)
Pagina fine
  • 3577 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 11 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento Chimica, CNR-ICCOM, Università di Bari, Dipartimento di Chimica Organica, Università di Pavia, Department of Chemistry, The University of Chicago and Department of Chemistry, Brown University (literal)
Titolo
  • Oxyfunctionalization of Non-Natural Targets by Dioxiranes. 6. On the Selective Hydroxylation of Cubane (literal)
Abstract
  • By using methyl(trifluoromethyl)dioxirane (TFDO), the direct mono- and bishydroxylation of cubane could be achieved in high yield under remarkably mild conditions. Comparison of the rates of dioxirane O-insertion with those of standard reference compounds, such as adamantine and cyclopropane, as well as ab initio computations provide useful hints concerning the mechanism of these transformations. (literal)
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