Selective B-H vs. N-H bond activation in ammonia borane by [Ir(dppm)2][OTf] (Articolo in rivista)

Type
Label
  • Selective B-H vs. N-H bond activation in ammonia borane by [Ir(dppm)2][OTf] (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/ejic.200900465 (literal)
Alternative label
  • Rossin, Andrea; Caporali, Maria; Gonsalvi, Luca; Guerri, Annalisa; Lledos, Agusti; Peruzzini, Maurizio; Zanobini, Fabrizio (2009)
    Selective B-H vs. N-H bond activation in ammonia borane by [Ir(dppm)2][OTf]
    in European journal of inorganic chemistry (Print); WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (Germania)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Rossin, Andrea; Caporali, Maria; Gonsalvi, Luca; Guerri, Annalisa; Lledos, Agusti; Peruzzini, Maurizio; Zanobini, Fabrizio (literal)
Pagina inizio
  • 3055 (literal)
Pagina fine
  • 3059 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICCOM-CNR; UAB Barcelona, Spain; Universita' di Firenze (literal)
Titolo
  • Selective B-H vs. N-H bond activation in ammonia borane by [Ir(dppm)2][OTf] (literal)
Abstract
  • Ammonia borane (AB, NH3·BH3) was activated selectively on the boron hydrogen atoms by [Ir(dppm)2]OTf, as shown by variable-temperature 31P, 11B and 1H NMR studies, to yield cis- and trans-[Ir(H)2(dppm)2]OTf dihydrides. X-ray crystal structures of these complexes were obtained. DFT calculations suggest the key reaction intermediate to be a Lewis base (L) stabilised adduct, cis-[Ir(H)(BH2·L)(dppm)2]+ (literal)
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