http://www.cnr.it/ontology/cnr/individuo/prodotto/ID16858
S-4(2-) Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure (Articolo in rivista)
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- S-4(2-) Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/anie.200705296 (literal)
- Alternative label
Mealli, Carlo; Ienco, Andrea; Poduska, Anne; Hoffmann, Roald (2008)
S-4(2-) Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure
in Angewandte Chemie (Int. ed., Print); WILEY-V C H VERLAG GMBH, WEINHEIM (Germania)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Mealli, Carlo; Ienco, Andrea; Poduska, Anne; Hoffmann, Roald (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://onlinelibrary.wiley.com/doi/10.1002/anie.200705296/abstract (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto di Chimica dei Composti Organometallici, ICCOM-CNR, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy); Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853-1301 (USA) (literal)
- Titolo
- S-4(2-) Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure (literal)
- Abstract
- Coming together, breaking apart: A theoretical analysis of the oxidative coupling of two metal-coordinated disulfide species to a S42- rectangle provides an opening to a reexamination of a number of compounds hitherto considered to be disulfide complexes. An electronic framework helps explain how the nature of the metal controls inner redox processes and the alternative stabilization of S42- or 2 S22- (or S2-) species. (literal)
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