Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-triaza-7-phosphatricyclo [3.3.1.13,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)] (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-triaza-7-phosphatricyclo [3.3.1.13,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)] (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ic701795y (literal)

Alternative label

• Erlandsson, Mikael; Gonsalvi, Luca; Ienco, Andrea; Peruzzini, Maurizio (2008)
  Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-triaza-7-phosphatricyclo [3.3.1.13,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)]
  in Inorganic chemistry (Online); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Erlandsson, Mikael; Gonsalvi, Luca; Ienco, Andrea; Peruzzini, Maurizio (literal)

Pagina inizio

• 8 (literal)

Pagina fine

• 10 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Corresponding Author (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021/ic701795y (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 47 (literal)

Rivista

• Inorganic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• iccom-cnr (literal)

Titolo

• Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-triaza-7-phosphatricyclo [3.3.1.13,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)] (literal)

Abstract

• A diastereomerically enriched analogue of 1,3,5-triaza-7-phosphaadamantane (PTA) was obtained by the reaction of PTA lithium salt with benzaldehyde to give the water-soluble derivative phenyl(1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]dec-6-yl)methanol (PZA, 1) as a mixture of two diastereoisomers. PZA derivatives phenyl(1,3,5-triaza-7-phospha-tricyclo[3.3.1.13,7]dec-6-yl)methanol sulfide [PZA(S), 2] and oxide [PZA(O), 3] were also synthesized. The latter was isolated in the solid state, and the X-ray crystal structure of a single diastereoisomer was obtained. Compound 1 was used as a k1-P monodentate ligand toward iridium(III) moieties, and the piano-stool complex [Cp*IrCl2(PZA)] (4) was obtained as a mixture of diastereoisomers both in solution and in the solid state. (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)

Autore CNR

• ANDREA IENCO (Persona)
• MAURIZIO PERUZZINI (Unità di personale interno)
• LUCA GONSALVI (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-triaza-7-phosphatricyclo [3.3.1.13,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)]" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)

Autore CNR di

• ANDREA IENCO (Persona)
• LUCA GONSALVI (Unità di personale interno)
• MAURIZIO PERUZZINI (Unità di personale interno)
• http://www.cnr.it/ontology/cnr/individuo/unitaDiPersonaleEsterno/ID5431

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry (Rivista)

Editore di

• ACS, American chemical society (Editore)

Insieme di parole chiave di

• Keywords of "Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-triaza-7-phosphatricyclo [3.3.1.13,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)]" (Insieme di parole chiave)