NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus (Articolo in rivista)

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  • NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/mrc.2344 (literal)
Alternative label
  • Caporali, Maria; Barbaro, Pierluigi; Bolaño, Sandra; Gonsalvi, Luca; Mañas-Carpio, Sonia; Peruzzini, Maurizio (2008)
    NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus
    in Magnetic resonance in chemistry (Print); John Wiley & Sons, Ltd., New York (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Caporali, Maria; Barbaro, Pierluigi; Bolaño, Sandra; Gonsalvi, Luca; Mañas-Carpio, Sonia; Peruzzini, Maurizio (literal)
Pagina inizio
  • s120 (literal)
Pagina fine
  • s125 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 46 (literal)
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  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICCOM-CNR (literal)
Titolo
  • NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus (literal)
Abstract
  • The solution structures of the novel heterobimetallic complexes [lr(dppm)(Ph2PCH2 PPh2 PPPP)(Pt(PPh3)2]OTf (1) and [Rh(dppm)(Ph2PCH2 PPh2 PPPP)(Pt(PPh3)2)]OTf (2) derived from the reaction of Rh and Ir-Ps precursors with [Pt(C2H4)(PPh3)2] have been unambiguously assigned on the basis of 1H NMR and 31C 1H NMR data. The results are in agreement with the regio-selective insertion of the [Pt(PPh3)2] moiety resulting in a new pentaphosphorus topology which agrees with the formal formation of a unique phosphonium(+)-tetraphosphabutadienide(2-) Iigand. (literal)
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