Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium-Coordinated 1-Hydroxytriphosphane by Hydrolysis of Doubly Metalated P4 (Articolo in rivista)

Type
Label
  • Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium-Coordinated 1-Hydroxytriphosphane by Hydrolysis of Doubly Metalated P4 (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/anie.200800723 (literal)
Alternative label
  • Barbaro Pierluigi; Di Vaira Massimo; Peruzzini Maurizio; Seniori Costantini Stefano; Stoppioni Piero (2008)
    Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium-Coordinated 1-Hydroxytriphosphane by Hydrolysis of Doubly Metalated P4
    in Angewandte Chemie (Int. ed., Print); Wiley-VCH Verlag, GmbH, Weinheim (Germania)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Barbaro Pierluigi; Di Vaira Massimo; Peruzzini Maurizio; Seniori Costantini Stefano; Stoppioni Piero (literal)
Pagina inizio
  • 4425 (literal)
Pagina fine
  • 4427 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
  • Highlighted in Nachrichten aus der Chemie, 2009, 57 (3), 222; GdCh publisher. (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 47 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Barbaro Pierluigi; Peruzzini Maurizio; Stoppioni Piero ICCOM - Istituto di chimica dei composti organo metallici Di Vaira Massimo; Seniori Costantini Stefano; Stoppioni Piero - Dipartimento di Chimica, Universit& di Firenze (literal)
Titolo
  • Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium-Coordinated 1-Hydroxytriphosphane by Hydrolysis of Doubly Metalated P4 (literal)
Abstract
  • When coordinated to two {CpRu(PPh3)2} moieties, white phosphorus (P4) reacts selectively with a large excess of water to yield phosphorous acid (H3PO3) and the previously unknown 1-hydroxytriphosphane (PH(OH)PHPH2), which is stabilized as a bridging ligand by coordination to the ruthenium moieties (literal)
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