XAS study of a Pt-containing rod-like organometallic polymer (Articolo in rivista)

Type
Label
  • XAS study of a Pt-containing rod-like organometallic polymer (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.chemphys.2006.01.014 (literal)
Alternative label
  • Battocchio, C (1); D'Acapito, F (1); Smolentsev, G (2); Soldatov, AV (2); Fratoddi, I (3); Contini, G (4); Davoli, I (5); Polzonetti, G (6); Mobilio, S (7) (2006)
    XAS study of a Pt-containing rod-like organometallic polymer
    in Chemical physics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Battocchio, C (1); D'Acapito, F (1); Smolentsev, G (2); Soldatov, AV (2); Fratoddi, I (3); Contini, G (4); Davoli, I (5); Polzonetti, G (6); Mobilio, S (7) (literal)
Pagina inizio
  • 422 (literal)
Pagina fine
  • 428 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 325 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • (1) CNR-INFM Ogg, c/o Care of ESRF, GILDA CRG, F-38043 Grenoble, France; (2) Rostov State University, Faculty Physics, Rostov Na Donu 344090, Russia; (3) University Roma La Sapienza, Department Chemistry, I-00185 Rome, Italy; (4) CNR-ISM, I-00133 Rome, Italy; (5) University of Rome Tor Vergata, Department Physics, INFM, I-00133 Rome, Italy; (6)University of Rome \"Roma Tre, Department of Physics and Unità INFM, INSTM and CISDiC, I-00146 Rome, Italy; (7) University of Rome \"Roma Tre, Department Physics, I-00146 Rome, Italy (literal)
Titolo
  • XAS study of a Pt-containing rod-like organometallic polymer (literal)
Abstract
  • The molecular structure of organometallic polymer Pt-DEBP [-Pt-4PBu(3))(2)-C C-C12H8-C C-](n), has been investigated by X-ray absorption spectroscopy (XAS). Data collected at the Pt-L-III edge of Pt-DEBP thick films spin-deposited onto Cr/Si(111) and Au/Si(111) substrates, have been analyzed to achieve information about the geometrical arrangement of the acetylene moieties and of the tributyl phosphine groups around the transition metal. The hypothesised square planar configuration of the ligands around the transition metal has been confirmed. From the comparison between the atomic distances in the pellet reference sample and in the film samples the self-assembling behaviour of the rod-like organometallic polymer, attributed to the predominant intermolecular forces, has been confirmed. (c) 2006 Elsevier B.V. All rights reserved. (literal)
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