KINETIC SOLVENT EFFECT ON PHENOLIC ANTIOXIDANTS DETERMINED BY SPECTROPHOTOMETRIC MEASUREMENTS (Articolo in rivista)

Type
Label
  • KINETIC SOLVENT EFFECT ON PHENOLIC ANTIOXIDANTS DETERMINED BY SPECTROPHOTOMETRIC MEASUREMENTS (Articolo in rivista) (literal)
Anno
  • 2001-01-01T00:00:00+01:00 (literal)
Alternative label
  • M. FOTI, G. RUBERTO (2001)
    KINETIC SOLVENT EFFECT ON PHENOLIC ANTIOXIDANTS DETERMINED BY SPECTROPHOTOMETRIC MEASUREMENTS
    in Journal of agricultural and food chemistry
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • M. FOTI, G. RUBERTO (literal)
Pagina inizio
  • 342 (literal)
Pagina fine
  • 348 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 49 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICB Catania (literal)
Titolo
  • KINETIC SOLVENT EFFECT ON PHENOLIC ANTIOXIDANTS DETERMINED BY SPECTROPHOTOMETRIC MEASUREMENTS (literal)
Abstract
  • The effects of polar (acetonitrile and tert-butyl alcohol) and apolar (cyclohexane) solvents on the peroxyl-radical-trapping antioxidant activity of some flavonoids, catechol derivatives, hydroquinone, and monophenols have been studied. The inhibition rate constant kinh of the antioxidants have been determined by following the increase in absorbance at 234 nm of a dilute solution of linoleic acid at 50 °C containing small amounts of antioxidant and radical initiator. Despite the low concentration of linoleic acid, the peroxidation process has been confirmed to be a free radical chain reaction described by the classi kinetic laws for this process. However, in the evaluation of kinh, a careful analysis of the peroxidation curve, absorbance versus time, must be done because the final oxidation products of phenols may absorb at 234 nm. Phenols with two ortho-hydroxyls are the most acttive antioxidants, with inhibition rate constants in the range (3-15) x 10(5) M(-1) s(-1) (in cyclohexane). Nevertheless, it has been observed that in tert-butyl alcohol (a strong hydrogen bond acceptor) the rate constants dramatically decline to values not detectable by the present kinetic method. In acetonitrile (a weaker hydrogen bond acceptor) instead, the phenols with two ortho-htdroxyls scavenge the peroxyl radicals with rate constants close to those in cyclohexane. From the kinetic solvent effect, the equilibrium constant of the first solvation step of hydroquinone with tert-butyl alcohol has been determined at 50 °C, K1 = 2.5 +/- 0.5 M(-1). (literal)
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