Synthesis, Reactivity, X-ray Crystal Structures and Electrochemical Behaviour of Water-Soluble [Tris(pyrazolyl)borato]ruthenium(II) Complexes of 1,3,5-Triaza-7-phosphaadamantane (PTA) (Articolo in rivista)

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  • Synthesis, Reactivity, X-ray Crystal Structures and Electrochemical Behaviour of Water-Soluble [Tris(pyrazolyl)borato]ruthenium(II) Complexes of 1,3,5-Triaza-7-phosphaadamantane (PTA) (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/ejic.200700672 (literal)
Alternative label
  • Bolaño, Sandra; Bravo, Jorge; Castro, Jesus; Rodríguez-Rocha, Maria Mar; Guedes da Silva, Maria F.C.; Pombeiro, Armando J.L.; Gonsalvi, Luca; Peruzzini, Maurizio (2007)
    Synthesis, Reactivity, X-ray Crystal Structures and Electrochemical Behaviour of Water-Soluble [Tris(pyrazolyl)borato]ruthenium(II) Complexes of 1,3,5-Triaza-7-phosphaadamantane (PTA)
    in European journal of inorganic chemistry (Print); WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (Germania)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bolaño, Sandra; Bravo, Jorge; Castro, Jesus; Rodríguez-Rocha, Maria Mar; Guedes da Silva, Maria F.C.; Pombeiro, Armando J.L.; Gonsalvi, Luca; Peruzzini, Maurizio (literal)
Pagina inizio
  • 5523 (literal)
Pagina fine
  • 5532 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICCOM-CNR; IST Lisbon, Portugal; Universidad de Vigo, Spagna (literal)
Titolo
  • Synthesis, Reactivity, X-ray Crystal Structures and Electrochemical Behaviour of Water-Soluble [Tris(pyrazolyl)borato]ruthenium(II) Complexes of 1,3,5-Triaza-7-phosphaadamantane (PTA) (literal)
Abstract
  • A series of chloridoruthenium(II) complexes bearing the tripodal ligand tris(pyrazolyl)borate (Tp), the water-soluble cage phosphane 1,3,5-triaza-7-phosphaadamantane (PTA) and its N-boranyl adduct PTA(BH3), together with PPh3, have been synthesised. The corresponding monohydrido complexes have also been obtained by treating the chlorides with NaOMe. The X-ray crystal structures of [TpRuCl(PTA)(PPh3)] (2) and [TpRuCl(PTA)2] (3) are also described. Cyclic voltammetry (CV) studies in MeCN and dmso generally show reversible RuII/III oxidation waves and the values of E1/2 ox reflect the electron-donating character of the ligands [Tp (each arm) ? PTA ? PTA(BH3)], whose Lever electrochemical parameter (EL) has been estimated for the first time (literal)
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