Barium Non-Stoichiometry Role on the Properties of Ba1+xCe0.65Zr0.20Y0.15O3–d Proton Conductors for IT-SOFCs (Articolo in rivista)

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  • Barium Non-Stoichiometry Role on the Properties of Ba1+xCe0.65Zr0.20Y0.15O3–d Proton Conductors for IT-SOFCs (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/fuce.200800021 (literal)
Alternative label
  • S. Barison; M. Battagliarin; T. Cavallin; S. Daolio; L. Doubova; M. Fabrizio; C. Mortalò; S. Boldrini; R. Gerbasi (2008)
    Barium Non-Stoichiometry Role on the Properties of Ba1+xCe0.65Zr0.20Y0.15O3–d Proton Conductors for IT-SOFCs
    in Fuel cells (Weinh., Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • S. Barison; M. Battagliarin; T. Cavallin; S. Daolio; L. Doubova; M. Fabrizio; C. Mortalò; S. Boldrini; R. Gerbasi (literal)
Pagina inizio
  • 360 (literal)
Pagina fine
  • 368 (literal)
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  • IF 2007 = 3.273 (literal)
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  • http://onlinelibrary.wiley.com/journal/10.1002/%28ISSN%291615-6854 (literal)
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  • 5 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
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  • CNR IENI,Corso Stati Uniti 4, 35127 Padova, Italy CNR ISIB,Corso StatiUniti 4, 35127 Padova, Italy CNR ICIS, Corso StatiUniti 4, 35127 Padova, Italy (literal)
Titolo
  • Barium Non-Stoichiometry Role on the Properties of Ba1+xCe0.65Zr0.20Y0.15O3–d Proton Conductors for IT-SOFCs (literal)
Abstract
  • Proton conducting perovskite oxides have been widely investigated because of their potential as electrolytes for intermediate temperature solid oxide fuel cells. Among them, BaCeO3- based materials exhibit good proton conductivity under a humidified hydrogen-containing atmosphere, but rather poor chemical stability in CO2 atmosphere. The substitution with Zr for Ce improves the chemical stability but reduces proton conductivity due to difficulties in fabricating dense materials. In the present work, single phase nanostructured powders of Ba1+xCe0.65Zr0.20Y0.15=3-g (x = 0, 0.05, 0.10) solid solutions have been prepared by a modified sol–gel Pechini method with the final aim of evaluating the role of barium on their chemical and electrical properties. A significant influence of barium excess on the preparation and on properties of these materials has been demonstrated. In fact, density measurements evidenced that a 5 or 10 mol% nominal barium excess sensibly favoured the sintering process. Impedance analyses of sintered pellets confirmed the necessity of barium excess in order to avoid the lowering of proton conductivity, which has been evidenced for samples having stoichiometric barium content. Moreover, an unforeseen increase in chemical stability in CO2-containing atmosphere with the growth of the barium excess was detected by thermogravimetric analyses. (literal)
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